Discovery of main group single Sb-N(4)active sites for CO(2)electroreduction to formate with high efficiency

doi:10.1039/d0ee01486a

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Discovery of main group single Sb-N(4)active sites for CO(2)electroreduction to formate with high efficiency
	Jiang, ZL ; Wang, T ; Pei, JJ ; Shang, HS ; Zhou, DN ; Li, HJ ; Dong, JC ; Wang, Y ; Cao, R ; Zhuang, ZB
刊名	ENERGY & ENVIRONMENTAL SCIENCE
	2020
卷号	13 期号:9 页码:2856-2863
关键词	CO2 REDUCTION CARBON-DIOXIDE FORMIC-ACID ELECTROCHEMICAL REDUCTION TIN CATALYSTS CONVERSION NANOWIRES
ISSN号	1754-5692
DOI	10.1039/d0ee01486a
文献子类	期刊论文
英文摘要	Main group antimony (Sb) species are promising electrocatalysts that promote the CO(2)reduction reaction (CO2RR) to formate, which is an important hydrogen storage material and a key chemical intermediate in many industrial reactions. Herein, we discovered that an Sb single atom (SA) material consisting of Sb-N(4)moieties anchored on N-doped carbon (NC) nanosheets (named Sb SA/NC) could serve as a CO2RR catalyst to produce formate with high efficiency. Sb SA/NC exhibited a formate faradaic efficiency of 94.0% at -0.8 Vvs.RHE.In situX-ray absorption fine structure (XAFS) investigations and density functional theory (DFT) calculations demonstrated that the excellent CO2RR activity originated from the positively charged Sb delta+-N-4(0
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/32799]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201800, Peoples R China 2.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Ma, Beijing 100081, Peoples R China 3.Stanford Univ, Dept Chem Engn, SUNCAT Ctr Interface Sci & Catalysis, Stanford, CA 94305 USA 4.Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China 5.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing, Peoples R China 6.SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA 7.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Jiang, ZL,Wang, T,Pei, JJ,et al. Discovery of main group single Sb-N(4)active sites for CO(2)electroreduction to formate with high efficiency[J]. ENERGY & ENVIRONMENTAL SCIENCE,2020,13(9):2856-2863.
APA	Jiang, ZL.,Wang, T.,Pei, JJ.,Shang, HS.,Zhou, DN.,...&Li, YD.(2020).Discovery of main group single Sb-N(4)active sites for CO(2)electroreduction to formate with high efficiency.ENERGY & ENVIRONMENTAL SCIENCE,13(9),2856-2863.
MLA	Jiang, ZL,et al."Discovery of main group single Sb-N(4)active sites for CO(2)electroreduction to formate with high efficiency".ENERGY & ENVIRONMENTAL SCIENCE 13.9(2020):2856-2863.