This study proposes a novel, to the best of our knowledge, development of fluorotellurite glass fiber Bragg gratings (FBGs). Shell-like morphology was achieved using a single femtosecond laser pulse illuminated through the fiber’s polymer coating. Different FBG fabrication methods and parameters were systematically studied to optimize performance. The fluorotellurite FBG exhibited a high sensitivity to writing laser power and reflectivity saturation effect in repetitive writing. A low-insertion-loss fluorotellurite FBG with a reflectivity of over 99% and bandwidth of less than 1 nm was successfully inscribed. The flexible inscription methods can write an FBG at any wavelength in the fluorotellurite glass transparent window, and are applicable to infrared fiber lasers or sensors. © 2021 Optical Society of America