Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts

doi:10.1002/slct.202003408

	Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts
	Cai, Chiliu 2,3,4; Xu, Jiangong 1; Wang, Haiyong 2,3,4; Xin, Haosheng 2,3,4; Zhang, Qi 2,3,4; Wang, Chenguang 2,3,4; Ma, Longlong 2,3,4; Liu, Qiying 2,3,4
刊名	CHEMISTRYSELECT
	2020-11-06
卷号	5 期号:41 页码:12785-12790
关键词	Au Mg(OH)(2) catalyst 5-hydroxymethyfufural Aerobic oxidation FDCA
ISSN号	2365-6549
DOI	10.1002/slct.202003408
通讯作者	Liu, Qiying(liugy@ms.giec.ac.cn)
英文摘要	2, 5-Furandicarboxylic acid (FDCA) obtained from selective 5-hydroxymethyfufural (HMF) oxidation is an important biodegradable polyester monomer and its production strongly depends on homogeneous base additives. The production of FDCA over solid base catalyst is green and environment-friendly. Herein, Au/Mg(OH)2 as the metal-solid base catalyst, was prepared by a simple colloidal method and applied to the oxidation of HMF. Detailed characterizations (XRD, TEM, XPS, TGA, CO2-TPD, etc.) were performed to uncover the structure-activity relationship of the catalyst. 92.6 % yield of FDCA was achieved under the optimal reaction condition. Moreover, a plausible mechanism for HMF oxidation over the metal-solid base catalyst was proposed by combining the surface properties of catalyst with the oxidation reaction results.
资助项目	National Key R&D Program of China[2019YFC1905303] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; National Natural Science Foundation of China[51976220] ; DNL Cooperation Fund, CAS[DNL180302]
WOS关键词	FREE AEROBIC OXIDATION ; 2,5-FURANDICARBOXYLIC ACID ; SELECTIVE OXIDATION ; BIOMASS ; CONVERSION ; EFFICIENT ; MG(OH)(2) ; CHEMICALS ; NANORODS ; MGO
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000586036200019
资助机构	National Key R&D Program of China ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/34862]
专题	中国科学院广州能源研究所
通讯作者	Liu, Qiying
作者单位	1.Xinxiang Med Coll, Affiliated Hosp 3, Xinxiang 453200, Henan, Peoples R China 2.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Cai, Chiliu,Xu, Jiangong,Wang, Haiyong,et al. Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts[J]. CHEMISTRYSELECT,2020,5(41):12785-12790.
APA	Cai, Chiliu.,Xu, Jiangong.,Wang, Haiyong.,Xin, Haosheng.,Zhang, Qi.,...&Liu, Qiying.(2020).Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts.CHEMISTRYSELECT,5(41),12785-12790.
MLA	Cai, Chiliu,et al."Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts".CHEMISTRYSELECT 5.41(2020):12785-12790.