PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material | |
Han, SJ (Han, Shujuan)[ 1,2 ]; Mutailipu, M (Mutailipu, Miriding)[ 1,2 ]; Tudi, A (Tudi, Abudukadi)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ] | |
刊名 | CHEMISTRY OF MATERIALS |
2020 | |
卷号 | 32期号:5页码:2172-2179 |
ISSN号 | 0897-4756 |
DOI | 10.1021/acs.chemmater.0c00150 |
英文摘要 | Nonlinear optical materials are the vital components of future photonic technologies as they can transfer and process data at the speed of light. However, the necessary prerequisites for a practical nonlinear optical material are very strict, and it is still a huge challenge to achieve the perfect balance among three critical parameters for nonlinear optics, including short cutoff edges, strong second-harmonic generation responses, and a suitable birefringence. Herein, via the introduction of the lone pair Pb2+ cations with stereochemical activity and the F- anions with the largest electronegativity into borate, a new fluorooxoborate PbB5O7F3 was obtained successfully. It exhibits a short cutoff edge (similar to 225 nm), a strong second-harmonic generation response (approximately 6 x KDP@1064 nm), and a large birefringence (cal. 0.12@1064 nm), achieving the optimal balance among the three critical parameters mentioned above for nonlinear optical applications in the short-wavelength region. The first-principles calculations were carried out to investigate the structure-property relationship of PbB5O7F3. |
WOS记录号 | WOS:000519337600044 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7289] |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Yang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ] |
作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Han, SJ ,Mutailipu, M ,Tudi, A ,et al. PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material[J]. CHEMISTRY OF MATERIALS,2020,32(5):2172-2179. |
APA | Han, SJ ,Mutailipu, M ,Tudi, A ,Yang, ZH ,&Pan, SL .(2020).PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material.CHEMISTRY OF MATERIALS,32(5),2172-2179. |
MLA | Han, SJ ,et al."PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material".CHEMISTRY OF MATERIALS 32.5(2020):2172-2179. |
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