(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties

doi:10.1021/acs.inorgchem.8b01017

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	(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties
	Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]; Pan, XB (Pan, Xiaobo)[ 1 ]; Han, SJ (Han, Shujuan)[ 1 ]; Rouzhahong, Y (Rouzhahong, Yilimiranmu)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Wu, HP (Wu, Hongping)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
刊名	INORGANIC CHEMISTRY
	2018
卷号	57 期号:12 页码:7372-7379
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.8b01017
英文摘要	By the application of cation substitution, five new members of cyclophosphates, RbCdP3O9, CsPbP3O9, CsSrP3O9, RbMgP3O9, and RbCaP3O9, were obtained by a high-temperature melt method and structurally analyzed. The five compounds have identical stoichiometries, and all of them feature a three-dimensional network, which consists of (MO6)-O-II (M-II = Cd, Mg, Ca, Pb, Sr) octahedra and cyclic P3O9 units, while alkali-metal atoms are located within the network. However, RbCdP3O9 and CsPbP(3)O(9)belong to the asymmetric space groups P (6) over bar c2 and Pna2(1) respectively, and the other three compounds belong to orthorhombic space group Pnma. Detailed structure comparisons in the M-I-M-II-P-O and ((MMP3O9)-M-I-P-II)(n) (n = 1, 2, 6) systems are discussed. Remarkably, KMgP3O9 as one of the cyclophosphate members exhibits a second harmonic generation (SHG) intensity about 0.2 times that of KH2PO4 (KDP), RbCdP3O9, and CsPbP3O9 also show SHG responses 0.1 times that of KDP. In addition, the related optical properties are discussed. Furthermore, theoretical calculations and dipole moments were calculated to explain the relation of structure and optical properties.
WOS记录号	WOS:000436023800066
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5785]
专题	新疆理化技术研究所_材料物理与化学研究室
通讯作者	Han, SJ (Han, Shujuan)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Abudoureheman, M ,Pan, XB ,Han, SJ ,et al. (MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties[J]. INORGANIC CHEMISTRY,2018,57(12):7372-7379.
APA	Abudoureheman, M .,Pan, XB .,Han, SJ .,Rouzhahong, Y .,Yang, ZH .,...&Pan, SL .(2018).(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties.INORGANIC CHEMISTRY,57(12),7372-7379.
MLA	Abudoureheman, M ,et al."(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties".INORGANIC CHEMISTRY 57.12(2018):7372-7379.