A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks | |
Yang Yun; Pan Shilie; Han Jian; Hou Xueling; Zhou Zhongxiang; Zhao Wenwu; Chen Zhaohui; Zhang Min | |
刊名 | CRYSTAL GROWTH & DESIGN |
2011 | |
卷号 | 11期号:9页码:3912-3916 |
ISSN号 | 1528-7483 |
DOI | 10.1021/cg200471b |
英文摘要 | A new noncentrosymmetric polyborate, Li6Rb5B 11O22, has been designed and synthesized in the Li 2O-Rb2O-B2O3 ternary system. The structure of the title compound was solved by single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group C2. The new structure contains an infinite three-dimensional matrix that is built from B 11O22 building blocks and LiOn (n = 4, 5), RbOn (n = 9, 10) polyhedra. The B11O22 building block has not been reported previously in any anhydrous and hydrated borates. The optical characterization of the compound indicates that its UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material. |
学科主题 | Chemistry ; Crystallography ; Materials Science |
WOS记录号 | WOS:000294647600037 |
公开日期 | 2012-11-29 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/1413] |
专题 | 新疆理化技术研究所_资源化学研究室 |
通讯作者 | Pan Shilie |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Coll Chem & Chem Engn, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Yang Yun,Pan Shilie,Han Jian,et al. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks[J]. CRYSTAL GROWTH & DESIGN,2011,11(9):3912-3916. |
APA | Yang Yun.,Pan Shilie.,Han Jian.,Hou Xueling.,Zhou Zhongxiang.,...&Zhang Min.(2011).A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks.CRYSTAL GROWTH & DESIGN,11(9),3912-3916. |
MLA | Yang Yun,et al."A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks".CRYSTAL GROWTH & DESIGN 11.9(2011):3912-3916. |
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