Diamond Deposition on Iron and Steel Substrates: A Review

doi:10.3390/mi11080719

CORC > 金属研究所 > 中国科学院金属研究所

	Diamond Deposition on Iron and Steel Substrates: A Review
	Li, Xiaoju 1; He, Lianlon 3; Li, Yuanshi 2; Yang, Qiaoqin 2
刊名	MICROMACHINES
	2020-08-01
卷号	11 期号:8 页码:21
关键词	CVD diamond diamond like carbon (DLC) steel carburization graphite interlayers Al alloying aluminizing siliconizing nucleation
DOI	10.3390/mi11080719
通讯作者	Li, Xiaoju(lixiaoju@sdu.edu.cn) ; Yang, Qiaoqin(yul088@mail.usask.ca)
英文摘要	This article presents an overview of the research in chemical vapor deposition (CVD) diamond films on steel substrates. Since the steels are the most commonly used and cost-effective structural materials in modern industry, CVD coating diamond films on steel substrates are extremely important, combining the unique surface properties of diamond with the superior toughness and strength of the core steel substrates, and will open up many new applications in the industry. However, CVD diamond deposition on steel substrates continues to be a persistent problem. We go through the most relevant results of the last two and a half decades, including recent advances in our group. This review discusses the essential reason of the thick catalytic graphite interlayer formed on steel substrates before diamond deposition. The high carbon diffusion in iron would induce severe internal carburization, and then voluminous graphite precipitated from the substrate. In order to hinder the catalytic graphite formation, various methods have been applied for the adherent diamond film deposition, such as pre-imposed various interlayers or multi-interlayers, special controls of the deposition process, the approaches of substrate alloying and so on. We found that adherent diamond films can be directly deposited on Al alloying steel substrates, and then the role of Al alloying element was examined. That is a thin dense amorphous alumina sublayer in situ formed on the alloying substrate, which played a critical role in preventing the formation of graphite phase and consequently enhancing diamond growth and adhesion. The mechanism of Al alloying suggests that the way used to improve hot corrosion resistance is also applicable. Then, some of the hot corrosion resistance methods, such as aluminizing, siliconizing, and so on, which have been used by some researchers examining CVD diamond films on steel substrates, are reviewed. Another way is to prepare diamond-like carbon (DLC) films on steel substrates at low temperature, and then the precipitated graphite from the internal carburization can be effectively avoided. In addition, based on some new findings, the understanding of the diamond nucleation and metastable growth is discussed.
资助项目	National Basic Research Program of China[2011CB605803] ; National Basic Research Program of China[2011CB605604] ; Canada Research Chair Program ; Natural Sciences and Engineering Research Council of Canada (NSERC) ; National Natural Science Foundation of China[41907105] ; Platform Innovative Foundation of the Institute of Microbial Technology
WOS研究方向	Science & Technology - Other Topics ; Instruments & Instrumentation
语种	英语
出版者	MDPI
WOS记录号	WOS:000577799500001
资助机构	National Basic Research Program of China ; Canada Research Chair Program ; Natural Sciences and Engineering Research Council of Canada (NSERC) ; National Natural Science Foundation of China ; Platform Innovative Foundation of the Institute of Microbial Technology
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/141029]
专题	金属研究所_中国科学院金属研究所
通讯作者	Li, Xiaoju; Yang, Qiaoqin
作者单位	1.Shandong Univ, State Key Lab Microbial Technol, Qingdao 266237, Peoples R China 2.Univ Saskatchewan, Dept Mech Engn, 57 Campus Dr, Saskatoon, SK S7N 5A9, Canada 3.Univ Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiaoju,He, Lianlon,Li, Yuanshi,et al. Diamond Deposition on Iron and Steel Substrates: A Review[J]. MICROMACHINES,2020,11(8):21.
APA	Li, Xiaoju,He, Lianlon,Li, Yuanshi,&Yang, Qiaoqin.(2020).Diamond Deposition on Iron and Steel Substrates: A Review.MICROMACHINES,11(8),21.
MLA	Li, Xiaoju,et al."Diamond Deposition on Iron and Steel Substrates: A Review".MICROMACHINES 11.8(2020):21.