On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions

doi:10.1016/j.cattod.2018.06.033

CORC > 金属研究所 > 中国科学院金属研究所

	On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions
	Ou, Xiaoxia 2; Pilitsis, Fotios 2; Xu, Ninghui 2,3; Taylor, S. F. Rebecca 2; Warren, John 1; Garforth, Arthur 2; Zhang, Jinsong 4; Hardacre, Christopher 2; Jiao, Yilai 2,4; Fan, Xiaolei 2
刊名	CATALYSIS TODAY
	2020-10-01
卷号	356 页码:631-640
关键词	Ferrisilicate SiC foams Structured catalyst Catalytic wet peroxide oxidation (CWPO)
ISSN号	0920-5861
DOI	10.1016/j.cattod.2018.06.033
通讯作者	Jiao, Yilai(yljiao@imr.ac.cn) ; Fan, Xiaolei(xiaolei.fan@manchester.ac.uk)
英文摘要	Fe supported catalysts show great promise for enabling practical environmental catalysis, exemplified by the catalytic wet peroxide oxidation (CWPO) process. In order to mitigate the Fe leaching issue, a strategy of assembling zeolitic coatings with intraframework Fe (ferrisilicate) on SiC foams was developed, showing a good stability in CWPO and a low Fe leaching of 2.0 mg l(-1). Direct hydrothermal synthesis of ferrisilicate/SiC foam composites was systematically studied, showing that their characteristics depend on the growth time, pH value and iron concentration of the growth solution. Selected ferrisilicate/SiC foam composite was evaluated using the continuous CWPO of phenolic aqueous solution at 60 degrees C. The open-cell size of SiC foam was varied between 800 and 2,000 mu m and showed insignificant effect on the hydrodynamics of the flow process at 1 ml min(-1), but the process efficiency in terms of phenol and total-organic-carbon (TOC) conversions was favored by a high surface-to-volume ratio (i.e. small open-cell sizes). Ferrisilicate/SiC foam catalysts (average open-cell size = 800 mu m) showed good stability in the model system with the stable conversions of phenol (97%), H2O2 (84%) and TOC (37%) over 24 h time-on-stream.
资助项目	Higher Education Innovation Fund `Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; China Scholarship Council (CSC)[201604910181] ; China Scholarship Council (CSC)[201408645064] ; EPSRC[EP/K014706/2] ; EPSRC[EP/K014668/1] ; EPSRC[EP/K014854/1] ; EPSRC[EP/K014714/1] ; EPSRC[EP/I019693/1]
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000579547900069
资助机构	Higher Education Innovation Fund `Knowledge and Innovation Hub for Environmental Sustainability' at The University of Manchester ; China Scholarship Council (CSC) ; EPSRC
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/140998]
专题	金属研究所_中国科学院金属研究所
通讯作者	Jiao, Yilai; Fan, Xiaolei
作者单位	1.Univ Manchester, Sch Mat, Oxford Rd, Manchester M13 9PL, Lancs, England 2.Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester M13 9PL, Lancs, England 3.Ningxia Orient Tantalum Ind Co Ltd, 119 Yejin Rd, Shizuishan City 753000, Ningxia, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Ou, Xiaoxia,Pilitsis, Fotios,Xu, Ninghui,et al. On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions[J]. CATALYSIS TODAY,2020,356:631-640.
APA	Ou, Xiaoxia.,Pilitsis, Fotios.,Xu, Ninghui.,Taylor, S. F. Rebecca.,Warren, John.,...&Fan, Xiaolei.(2020).On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions.CATALYSIS TODAY,356,631-640.
MLA	Ou, Xiaoxia,et al."On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions".CATALYSIS TODAY 356(2020):631-640.