Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions

doi:10.1016/j.micromeso.2020.110254

CORC > 金属研究所 > 中国科学院金属研究所

	Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions
	Wang, Sha 1; Wang, Tieqiang 1; Zheng, Huayu 1; Fan, Fuqiang 1; Gu, Zhida 1; He, Wenxiu 1; Zhang, Bing 1; Shao, Lei 1; Chen, Huan 1; Li, Yunong 1
刊名	MICROPOROUS AND MESOPOROUS MATERIALS
	2020-08-15
卷号	303 页码:7
关键词	Mesoporous 2D MOF nanosheets Ultrathin C-S cross-coupling reaction
ISSN号	1387-1811
DOI	10.1016/j.micromeso.2020.110254
通讯作者	Fu, Yu(fuyu@mail.neu.edu.cn) ; Qi, Wei(wqi@imr.ac.cn)
英文摘要	Pore size enlargement plays a vital role in the catalytic applications of metal-organic frameworks (MOFs). There is still a big challenge in achieving two-dimension (2D) ultrathin MOF nanosheets with controllable meso-pores, although it has huge demanding. In this work, various kinds of mesoporous MOF nanosheets with uniform mesopore channels and crystallized microporous frameworks were constructed using surfactants (cetyltrimethyl ammonium bromide, CTAB) as sacrificial templates. CTAB was firstly introduced into MOF nanosheet structure during the formation of MOF nanosheets, and mesopores could be produced by removing CTAB from MOF nanosheets. Remarkably, the integration of ultrathin nanosheets and mesoporous property enables mesoporous CuBDC nanosheets enhanced catalytic activity for C-S cross-coupling reaction, providing a new concept and feasible strategy for highly efficient mesoporous MOF catalyst synthesis.
资助项目	National Natural Science Foundation of China[21761132010] ; National Natural Science Foundation of China[91645114] ; National Natural Science Foundation of China[21573256] ; National Natural Science Foundation of China[21805028] ; National Natural Science Foundation of China[21805029] ; Fundamental Research Funds for the Central Universities[N160504002] ; Fundamental Research Funds for the Central Universities[N170503010] ; Fundamental Research Funds for the Central Universities[N180705004] ; Fundamental Research Funds for the Central Universities[N180504005] ; Fundamental Research Funds for the Central Universities[N180504007] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202008] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202042] ; Open Project of State Key Laboratory of Supramolecular Structure and Materials[sklssm202027]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000535938200015
资助机构	National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Open Project of State Key Laboratory of Supramolecular Structure and Materials
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/139034]
专题	金属研究所_中国科学院金属研究所
通讯作者	Fu, Yu; Qi, Wei
作者单位	1.Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Wang, Sha,Wang, Tieqiang,Zheng, Huayu,et al. Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2020,303:7.
APA	Wang, Sha.,Wang, Tieqiang.,Zheng, Huayu.,Fan, Fuqiang.,Gu, Zhida.,...&Qi, Wei.(2020).Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions.MICROPOROUS AND MESOPOROUS MATERIALS,303,7.
MLA	Wang, Sha,et al."Fabrication of mesoporous MOF nanosheets via surfactant-template method for C-S coupling reactions".MICROPOROUS AND MESOPOROUS MATERIALS 303(2020):7.