Evolution and Growth Mechanism of Cu-2(In,Sn) Formed Between In-48Sn Solder and Polycrystalline Cu During Long-Time Liquid-State Aging | |
Tian, Feifei2,3; Pang, Xueyong1; Xu, Bo2; Liu, Zhi-Quan3,4 | |
刊名 | JOURNAL OF ELECTRONIC MATERIALS |
2020-01-02 | |
卷号 | 49期号:4页码:9 |
关键词 | In-48Sn solder polycrystalline Cu Cu-2(In Sn) growth orientation |
ISSN号 | 0361-5235 |
DOI | 10.1007/s11664-019-07909-w |
通讯作者 | Liu, Zhi-Quan(zqliu@siat.ac.cn) |
英文摘要 | Evolution of Cu-2(In,Sn) formed between In-48Sn solder and polycrystalline Cu during long-time liquid-state aging was systematically investigated. During aging at 160 degrees C up to 90 min, one IMC species, Cu-2(In,Sn) was found, which showed two different morphologies, a coarse-grained Cu-2(In,Sn) sublayer and a fine-grained Cu2(In,Sn) sublayer. The fine Cu-2(In,Sn) grains had and always kept a granular morphology without any growth orientation. The morphology of coarse Cu-2(In,Sn) grains evolved from poly-facet pyramidal-type without preferential orientation into hexagonal structure preferring only one elongated direction after aging up to 90 min. Electron beam backscattered diffraction revealed that coarse-grain Cu-2(In,Sn) compound grew along [0001] axis and exposed {11-20} crystal planes. Growth mechanism of coarse Cu-2(In,Sn) grains related closely to thermodynamic stability of hexagonal structure, which drove by reduction of surface energy from higher to lower, and first principles calculations verified that {11-20} crystal planes had the lowest surface energy. Fine Cu-2(In,Sn) grains had a special growth mechanism at the root of coarse Cu-2(In,Sn) grains compared to normal fine Cu-2(In,Sn) grains underneath coarse Cu-2(In,Sn) grains. |
资助项目 | National Key R&D Program of China[2017YFB0305700] ; fundamental research funds for the Central Universities[N160208001] |
WOS研究方向 | Engineering ; Materials Science ; Physics |
语种 | 英语 |
出版者 | SPRINGER |
WOS记录号 | WOS:000505344800016 |
资助机构 | National Key R&D Program of China ; fundamental research funds for the Central Universities |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/136508] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Liu, Zhi-Quan |
作者单位 | 1.Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Liaoning, Peoples R China 2.Nanjing Elect Devices Inst, Nanjing 210016, Jiangsu, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China 4.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Tian, Feifei,Pang, Xueyong,Xu, Bo,et al. Evolution and Growth Mechanism of Cu-2(In,Sn) Formed Between In-48Sn Solder and Polycrystalline Cu During Long-Time Liquid-State Aging[J]. JOURNAL OF ELECTRONIC MATERIALS,2020,49(4):9. |
APA | Tian, Feifei,Pang, Xueyong,Xu, Bo,&Liu, Zhi-Quan.(2020).Evolution and Growth Mechanism of Cu-2(In,Sn) Formed Between In-48Sn Solder and Polycrystalline Cu During Long-Time Liquid-State Aging.JOURNAL OF ELECTRONIC MATERIALS,49(4),9. |
MLA | Tian, Feifei,et al."Evolution and Growth Mechanism of Cu-2(In,Sn) Formed Between In-48Sn Solder and Polycrystalline Cu During Long-Time Liquid-State Aging".JOURNAL OF ELECTRONIC MATERIALS 49.4(2020):9. |
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