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Effect of MgCl2 on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition
Pan, Chen; Guo, Mingxiao; Wang, Zhenyao
刊名JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
2019-05-01
卷号28期号:5页码:2562-2572
关键词atmospheric corrosion copper in situ electrochemical impedance spectroscopy MgCl2
ISSN号1059-9495
DOI10.1007/s11665-019-04058-3
通讯作者Pan, Chen(cpan@imr.ac.cn)
英文摘要The corrosion behaviors of copper under periodic wet/dry cycle conditions were investigated. The characteristics of the corrosion product formed on copper were analyzed by x-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and in situ electrochemical impedance spectroscopy. Weight loss results showed that the corrosion of copper under an MgCl2 deposition condition was more severe than that under NaCl. The main corrosion products formed on the tested sample under NaCl deposition condition consisted of Cu2Cl(OH)(3) and Cu2O, while those under the MgCl2 deposition condition consisted of Cu2Cl(OH)(3) and Mg-2(OH)(3)Cl4H(2)O. In the case of the NaCl deposition condition, a two-layered structure formed during the corrosion process. However, the corrosion product layer formed on copper under the MgCl2 deposition condition had an extremely loose structure. The effect of MgCl2 on the corrosion mechanism of copper is discussed.
资助项目National Science Foundation of China[51601199] ; National Science Foundation of China[51671197] ; Guangzhou Industry-university-research Collaborative Innovation Alliance Special Project[201604046014]
WOS研究方向Materials Science
语种英语
出版者SPRINGER
WOS记录号WOS:000468800800008
资助机构National Science Foundation of China ; Guangzhou Industry-university-research Collaborative Innovation Alliance Special Project
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/133530]  
专题金属研究所_中国科学院金属研究所
通讯作者Pan, Chen
作者单位Chinese Acad Sci, Environm Corros Ctr, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Pan, Chen,Guo, Mingxiao,Wang, Zhenyao. Effect of MgCl2 on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition[J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,2019,28(5):2562-2572.
APA Pan, Chen,Guo, Mingxiao,&Wang, Zhenyao.(2019).Effect of MgCl2 on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition.JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,28(5),2562-2572.
MLA Pan, Chen,et al."Effect of MgCl2 on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition".JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE 28.5(2019):2562-2572.
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