Ceramic phases with one-dimensional long-range order | |
Yin, Deqiang2,3; Chen, Chunlin2,4; Saito, Mitsuhiro1,2; Inoue, Kazutoshi2; Ikuhara, Yuichi1,2,5 | |
刊名 | NATURE MATERIALS |
2019 | |
卷号 | 18期号:1页码:19-+ |
ISSN号 | 1476-1122 |
DOI | 10.1038/s41563-018-0240-0 |
通讯作者 | Chen, Chunlin(clchen@imr.ac.cn) ; Ikuhara, Yuichi(ikuhara@sigma.t.u-tokyo.ac.jp) |
英文摘要 | Solids are generally classified into three categories based on their atomic arrangement: crystalline, quasicrystalline and amorphous(1-4). Here we report MgO and Nd2O3 ceramic phases with special atomic arrangements that should belong to a category of solids different from these three well known categories by combining state-of-the-art atomic-resolution scanning transmission electron microscopy and first-principles calculations. The reported solid structure exhibits a one-dimensional (1D) long-range order with a translational periodicity and is composed of structural units that individually have atomic arrangements similar to those observed in coincidence-site lattice configurations present at grain boundaries. Regardless of the insulating nature of the bulk MgO, the bandgap of which is measured to be 7.4 eV, the MgO 1D ordered structure is a wide-bandgap semiconductor with a bandgap of 3.2 eV owing to this special atomic arrangement. The discovery of 1D ordered structures suggests that the structural categories of solids could be more abundant, with physical properties distinct from their regular counterparts. |
资助项目 | Japan Society for the Promotion of Science (JSPS)[JP17H06094] ; MEXT[12024046] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC027] ; National Natural Sciences Foundation of China[51771200] ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China[11332013] |
WOS研究方向 | Chemistry ; Materials Science ; Physics |
语种 | 英语 |
出版者 | NATURE PUBLISHING GROUP |
WOS记录号 | WOS:000452876200010 |
资助机构 | Japan Society for the Promotion of Science (JSPS) ; MEXT ; Key Research Program of Frontier Sciences, CAS ; National Natural Sciences Foundation of China ; 'Thousand Youth Talents Plan' of China ; National Natural Science Foundation of China |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/130846] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Chen, Chunlin; Ikuhara, Yuichi |
作者单位 | 1.Univ Tokyo, Inst Engn Innovat, Bunkyo Ku, Tokyo, Japan 2.Tohoku Univ, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi, Japan 3.Chongqing Univ, Coll Aerosp Engn, Chongqing, Peoples R China 4.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang, Liaoning, Peoples R China 5.Japan Fine Ceram Ctr, Nanostruct Res Lab, Atsuta Ku, Nagoya, Aichi, Japan |
推荐引用方式 GB/T 7714 | Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,et al. Ceramic phases with one-dimensional long-range order[J]. NATURE MATERIALS,2019,18(1):19-+. |
APA | Yin, Deqiang,Chen, Chunlin,Saito, Mitsuhiro,Inoue, Kazutoshi,&Ikuhara, Yuichi.(2019).Ceramic phases with one-dimensional long-range order.NATURE MATERIALS,18(1),19-+. |
MLA | Yin, Deqiang,et al."Ceramic phases with one-dimensional long-range order".NATURE MATERIALS 18.1(2019):19-+. |
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