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Oxidation Behavior of NiFe2O4 Spinel-Coated Interconnects in Wet Air
You, Peng Fei1,2; Zhang, Xue1; Zhang, Hai Liang1,2; Zeng, Chao Liu1
刊名OXIDATION OF METALS
2018-10-01
卷号90期号:3-4页码:499-513
关键词Solid oxide fuel cell Ferritic stainless steel Interconnect NiFe2O4 spinel coating Wet air Oxidation
ISSN号0030-770X
DOI10.1007/s11085-018-9851-8
通讯作者Zhang, Xue(xuezhang@imr.ac.cn)
英文摘要Ferritic stainless steels are promising materials for solid oxide fuel cell interconnect applications. However, volatilization of Cr from the Cr-containing oxide scales can result in cathode poisoning, especially in wet air, and thus greatly degrades the performances of the cell. In the present study, a protective and adhesive NiFe2O4 spinel coating was applied on a type 430 stainless steel (430SS) to isolate Cr2O3 from gas environment. The performance of the uncoated and NiFe2O4-coated samples has been evaluated in the air-7%H2O at 700, 800, and 850 degrees C, respectively. The bare steel lost mass at 700 and 800 degrees C and underwent breakaway oxidation at 850 degrees C after 75h, including scale spallation and Cr evaporation. The NiFe2O4 coating could significantly increase the oxidation resistance of 430SS and effectively retard the outward diffusion of Cr and inhibit the Cr evaporation.
资助项目National Natural Science Foundation of China[51471179] ; National Natural Science Foundation of China[51601202]
WOS研究方向Metallurgy & Metallurgical Engineering
语种英语
出版者SPRINGER/PLENUM PUBLISHERS
WOS记录号WOS:000444007200016
资助机构National Natural Science Foundation of China
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/129510]  
专题金属研究所_中国科学院金属研究所
通讯作者Zhang, Xue
作者单位1.Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, 62 Wencui Rd, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, 96 JinZhai Rd, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
You, Peng Fei,Zhang, Xue,Zhang, Hai Liang,et al. Oxidation Behavior of NiFe2O4 Spinel-Coated Interconnects in Wet Air[J]. OXIDATION OF METALS,2018,90(3-4):499-513.
APA You, Peng Fei,Zhang, Xue,Zhang, Hai Liang,&Zeng, Chao Liu.(2018).Oxidation Behavior of NiFe2O4 Spinel-Coated Interconnects in Wet Air.OXIDATION OF METALS,90(3-4),499-513.
MLA You, Peng Fei,et al."Oxidation Behavior of NiFe2O4 Spinel-Coated Interconnects in Wet Air".OXIDATION OF METALS 90.3-4(2018):499-513.
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