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Synthesis and properties of Na0.8Ni0.4Mn0.6O2 oxide used as cathode material for sodium ion batteries
Liu, Guo-Qiang1,2; Li, Yue1; Du, Yu-Long1; Wen, Lei3
刊名RARE METALS
2017-12-01
卷号36期号:12页码:977-980
关键词Sodium ion batteries Na0.8Ni0.4Mn0.6O2 oxide Cathode Electrochemical properties
ISSN号1001-0521
DOI10.1007/s12598-016-0757-9
通讯作者Liu, Guo-Qiang(liugq@smm.neu.edu.cn)
英文摘要A new P2-structured oxide Na0.8Ni0.4Mn0.6O2 was synthesized using a solid reaction method in which Na2CO3, MnO2 and NiO were used as starting materials. This oxide has a high amount of electrochemically active Ni and exhibits good electrochemical intercalation behavior of Na ions, including good rate capability and good cycle performance at both room temperature and elevated temperature. It displays two apparent voltage plateaus at about 3.6 and 3.3 V, and its discharge capacity reaches 92 mAh center dot g(-1) at 0.1C in the voltage range of 2.0-4.0 V. At 1.0C, its discharge capacity reaches 85.3 mAh center dot g(-1). After 80 cycles at different current rates, the as-prepared sample exhibits good capacity retention. At elevated temperature of 55 A degrees C, the discharge capacity remains the same at low current rate of 0.1C, but at high current rate of 1.0C, the discharge capacity is a little lower than that at room temperature.
资助项目National Natural Science Foundation of China[51574081] ; Natural Science Foundation of Liaoning Province[2014020035]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者NONFERROUS METALS SOC CHINA
WOS记录号WOS:000414730400007
资助机构National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/125365]  
专题金属研究所_中国科学院金属研究所
通讯作者Liu, Guo-Qiang
作者单位1.Northeastern Univ, Sch Met & Mat, Shenyang 110819, Liaoning, Peoples R China
2.Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Liu, Guo-Qiang,Li, Yue,Du, Yu-Long,et al. Synthesis and properties of Na0.8Ni0.4Mn0.6O2 oxide used as cathode material for sodium ion batteries[J]. RARE METALS,2017,36(12):977-980.
APA Liu, Guo-Qiang,Li, Yue,Du, Yu-Long,&Wen, Lei.(2017).Synthesis and properties of Na0.8Ni0.4Mn0.6O2 oxide used as cathode material for sodium ion batteries.RARE METALS,36(12),977-980.
MLA Liu, Guo-Qiang,et al."Synthesis and properties of Na0.8Ni0.4Mn0.6O2 oxide used as cathode material for sodium ion batteries".RARE METALS 36.12(2017):977-980.
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