Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O

doi:10.1002/crat.201000231

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	Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O
	Yang, Wei-Qing 1,3; Zheng, Wen-Chen 1,2; Liu, Hong-Gang 1
刊名	CRYSTAL RESEARCH AND TECHNOLOGY
	2010-08-01
卷号	45 期号:8 页码:863-866
关键词	electron paramagnetic resonance crystal-field theory spin-Hamiltonian parameters Dy3+ La2Mg3(NO3)(12)center dot 24H(2)O
ISSN号	0232-1300
DOI	10.1002/crat.201000231
通讯作者	Zheng, Wen-Chen(zhengwc1@163.com)
英文摘要	The spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants (161)A(parallel to), (161)A(perpendicular to), (163)A(parallel to), (163)A(perpendicular to)) for Dy-161(3+) and Dy-163(3+) isotopes in the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman and hyperfine interaction terms are added to the conventional Hamiltonian used in the studies of crystal-field energy levels, and a 66x66 energy matrix concerning the ground multiplet H-6(15/2) and the first to fifth excited multiplets H-6(13/2), H-6(11/2), H-6(9/2), H-6(7/2) and H-6(5/2) are applied. The calculated results are discussed. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
资助项目	ICMP, CAS[ICMP 2009001]
WOS研究方向	Crystallography
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000280674600014
资助机构	ICMP, CAS
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/103009]
专题	金属研究所_中国科学院金属研究所
通讯作者	Zheng, Wen-Chen
作者单位	1.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Peoples R China 2.Chinese Acad Sci, Int Ctr Mat Phys, Shenyang 110016, Peoples R China 3.Chengdu Univ Informat Technol, Dept Opt & Elect, Chengdu 610225, Peoples R China
推荐引用方式 GB/T 7714	Yang, Wei-Qing,Zheng, Wen-Chen,Liu, Hong-Gang. Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O[J]. CRYSTAL RESEARCH AND TECHNOLOGY,2010,45(8):863-866.
APA	Yang, Wei-Qing,Zheng, Wen-Chen,&Liu, Hong-Gang.(2010).Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O.CRYSTAL RESEARCH AND TECHNOLOGY,45(8),863-866.
MLA	Yang, Wei-Qing,et al."Spin-Hamiltonian parameters for Dy3+ ion at the trigonal 12-fold coordinated La3+ site of La2Mg3(NO3)(12)center dot 24H(2)O".CRYSTAL RESEARCH AND TECHNOLOGY 45.8(2010):863-866.