Anaerobically-digested sludge conditioning by activated peroxymonosulfate: Significance of EDTA chelated-Fe2+

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 中国科学院饮用水科学与技术重点实验室

	Anaerobically-digested sludge conditioning by activated peroxymonosulfate: Significance of EDTA chelated-Fe2+
	Wang, Jiaqi ; Yang, Min ; Liu, Ruiping ; Hu, Chengzhi ; Liu, Huijuan ; Qu, Jiuhui
刊名	WATER RESEARCH
	2019-09-01
卷号	160 页码:454-465
关键词	Anaerobically-digested sludge Dewaterability Peroxymonosulfate activation EDTA chelated-Fe2+ Extracellular polymeric substances
ISSN号	0043-1354
英文摘要	This study investigates the efficiency of anaerobically-digested sludge (ADS) conditioning using peroxymonosulfate (PMS) activated by EDTA chelated-Fe2+ process (PMS-EDTA-Fe2+), and the roles and mechanism of EDTA are explored by investigating the capillary suction time (CST), specific resistance to filtration (SRF), bound water content (BWC), extracellular polymeric substances (EPS), iron species transformation, sludge morphology, and active radicals formation. PMS-EDTA-Fe2+ process exhibits better performance in sludge dewatering than PMS-Fe2+ process. Upon the introduction of EDTA at optimum molar ratio of EDTA to Fe2+ (R(EDTA:Fe)2+) of 1 : 3, CST, SRF, and BWC are decreased by 60.0%, 70.6%, and 1.5%, and the cell viability is decreased from 75.4% to as low as 24.7%. EDTA introduction significantly enhances the yield of active radicals (i.e., SO4-center dot and (OH)-O-center dot) by nearly 50% as compared to PMS-Fe2+ process. This effect contributes to stronger cells lysis as indicated by SEM and CLSM, and the contents of polysaccharide and protein in total EPS fractions are increased by 19.2% and 37.4% accordingly. Additionally, EDTA increases the iron mobility by forming Fe-II/III-EDTA complexes and potentially inhibits ADS coagulation at high doses. The total dissolved iron (Fe-Tot_(dis)) concentration increases from 203.4 mg/L to 601.4 mg/L due to the introduction of EDTA at 0.4 mmol/g VSS, and the dominant iron species in supernatant transformed from Fe2+ to Fe3+ accordingly. The optimization of EDTA doses is significant to balance oxidation and coagulation effects and to achieve better dewatering performance. (C) 2019 Elsevier Ltd. All rights reserved.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/43421]
专题	生态环境研究中心_中国科学院饮用水科学与技术重点实验室
作者单位	1.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, Key Lab Drinking Water Sci & Technol, Beijing 100085, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tsinghua Univ, Sch Environm, Ctr Water & Ecol, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Wang, Jiaqi,Yang, Min,Liu, Ruiping,et al. Anaerobically-digested sludge conditioning by activated peroxymonosulfate: Significance of EDTA chelated-Fe2+[J]. WATER RESEARCH,2019,160:454-465.
APA	Wang, Jiaqi,Yang, Min,Liu, Ruiping,Hu, Chengzhi,Liu, Huijuan,&Qu, Jiuhui.(2019).Anaerobically-digested sludge conditioning by activated peroxymonosulfate: Significance of EDTA chelated-Fe2+.WATER RESEARCH,160,454-465.
MLA	Wang, Jiaqi,et al."Anaerobically-digested sludge conditioning by activated peroxymonosulfate: Significance of EDTA chelated-Fe2+".WATER RESEARCH 160(2019):454-465.