Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates

doi:10.1002/cctc.201901167

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates
	Sun, QM ; Fu, XP ; Si, R ; Wang, CH ; Yan, N
刊名	CHEMCATCHEM
	2019
卷号	11 期号:20 页码:5093-5097
关键词	FORMIC-ACID PD CATALYSTS NANOPARTICLES METHANOL PERFORMANCE COMPLEXES SUPPORT PHENOL STEP
ISSN号	1867-3880
DOI	10.1002/cctc.201901167
文献子类	期刊论文
英文摘要	CO2 hydrogenation to formic acid/formate has been recognized as a key reaction to realizing the CO2-mediated hydrogen energy cycle. Herein, ultrafine and well-dispersed Pd-CoO nanoparticles (similar to 1.8 nm) were encapsulated within mesoporous silica nanospheres (MSNs) via a facile one-pot ligand-protected synthesis strategy. The MSN-encaged bimetallic nanocatalysts exhibit excellent catalytic activity and stability for the formate production from CO2 hydrogenation, showing high turnover frequency value up to 1824 h(-1) at 373 K, which is among the top-level reported for heterogeneous catalysts.
语种	英语
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/32132]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Natl Univ Singapore, Environm Res Inst NERI, Singapore 138602, Singapore; 2.Natl Univ Singapore, Dept Chem & Biomol Engn, 4 Engn Dr 4, Singapore 117585, Singapore; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式 GB/T 7714	Sun, QM,Fu, XP,Si, R,et al. Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates[J]. CHEMCATCHEM,2019,11(20):5093-5097.
APA	Sun, QM,Fu, XP,Si, R,Wang, CH,&Yan, N.(2019).Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates.CHEMCATCHEM,11(20),5093-5097.
MLA	Sun, QM,et al."Mesoporous Silica-Encaged Ultrafine Bimetallic Nanocatalysts for CO2 Hydrogenation to Formates".CHEMCATCHEM 11.20(2019):5093-5097.