Superior to graphene: super-anticorrosive natural mica nanosheets
Ding, Jiheng; Zhao, Hongran; Yu, Haibin
刊名NANOSCALE
2020
卷号12期号:30页码:16253-16261
关键词EPOXY-RESIN OXIDE EXFOLIATION PERFORMANCE OXIDATION COATINGS
DOI10.1039/d0nr05040g
英文摘要Graphene has been generally considered to be the most ideal anticorrosive material based on its extraordinary impermeability, but tends in practical applications to promote metal corrosion because of its inherently high electrical conductivity. Mica nanosheets (MNSs), in contrast, display excellent electrical insulation properties, as well as excellent temperature stability and chemical durability, and show tremendous potential for protecting metals, and hence are a promising substitute for graphene. To date, however, there have been no reports about MNS-based anticorrosive coatings, since it is much more difficult to exfoliate high-quality MNSs than other layered materials. In this work, high-concentration (4.3 mg ml(-1)) ultrathin MNS (1-5 layers) dispersions were synthesized based on a facile and efficient hydrothermal exfoliation approach. Epoxy (EP) coatings were filled with the as-obtained MNSs to enhance the anticorrosion performance of the coatings, and their corrosion behaviors were studied systemically through a series of measurements. With the addition of only 0.4 wt% MNSs, the corrosion rate was observed to be reduced 6500 fold, and the coating impedance increased by four orders of magnitude compared with the blank EP coating. We believe that this method opens a novel avenue for developing high-performance anticorrosive coatings to replace graphene materials for metal protection.
学科主题Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20586]  
专题2020专题
作者单位1.Ding, JH
2.Yu, HB (corresponding author), Chinese Acad Sci, Zhejiang Key Lab Marine Mat & Protect Technol, Ningbo Inst Mat Technol & Engn, Univ Chinese Acad Sci,Key Lab Marine Mat & Relate, Ningbo 315201, Peoples R China.
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GB/T 7714
Ding, Jiheng,Zhao, Hongran,Yu, Haibin. Superior to graphene: super-anticorrosive natural mica nanosheets[J]. NANOSCALE,2020,12(30):16253-16261.
APA Ding, Jiheng,Zhao, Hongran,&Yu, Haibin.(2020).Superior to graphene: super-anticorrosive natural mica nanosheets.NANOSCALE,12(30),16253-16261.
MLA Ding, Jiheng,et al."Superior to graphene: super-anticorrosive natural mica nanosheets".NANOSCALE 12.30(2020):16253-16261.
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