Advanced electrochemical treatment of real biotreated petrochemical wastewater by boron doped diamond anode: performance, kinetics, and degradation mechanism
Li, Hao; Kuang, Xinmou; Qiu, Congping; Shen, Xiaolan; Zhang, Botao; Li, Hua
刊名WATER SCIENCE AND TECHNOLOGY
2020
卷号82期号:4页码:773-786
关键词PETROLEUM-HYDROCARBONS OXIDATION DECONTAMINATION MINERALIZATION WASTEWATERS TECHNOLOGY EFFLUENT
DOI10.2166/wst.2020.387
英文摘要Petrochemical wastewater is difficult to process because of various types of pollutants with high toxicity. With the improvement in the national discharge standard, traditional biochemical treatment methods may not meet the standards and further advanced treatment techniques would be required. In this study, electrochemical oxidation with boron doped diamond (BDD) anode as post-treatment was carried out for the treatment of real biotreated petrochemical wastewater. The effects of current density, pH value, agitation rate, and anode materials on chemical oxygen demand (COD) removal and current efficiency were studied. The results revealed the appropriate conditions to be a current density of 10 mA.cm(-2), a pH value of 3, and an agitation rate of 400 rpm. Moreover, as compared with the graphite electrode, the BDD electrode had a higher oxidation efficiency and COD removal efficiency. Furthermore, GC-MS was used to analyze the final degradation products, in which ammonium chloride, formic acid, acetic acid, and malonic acid were detected. Finally, the energy consumption was estimated to be 6.24 kWh.m(-3) with a final COD of 30.2 mg.L-1 at a current density of 10 mA.cm(-2) without the addition of extra substances. This study provides an alternative for the upgrading of petrochemical wastewater treatment plants.
学科主题Engineering ; Environmental Sciences & Ecology ; Water Resources
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/20577]  
专题2020专题
作者单位Li, H (corresponding author), Ningbo Polytech, Zhejiang Collaborat Innovat Ctr High Value Utiliz, Ningbo 315800, Peoples R China.
推荐引用方式
GB/T 7714
Li, Hao,Kuang, Xinmou,Qiu, Congping,et al. Advanced electrochemical treatment of real biotreated petrochemical wastewater by boron doped diamond anode: performance, kinetics, and degradation mechanism[J]. WATER SCIENCE AND TECHNOLOGY,2020,82(4):773-786.
APA Li, Hao,Kuang, Xinmou,Qiu, Congping,Shen, Xiaolan,Zhang, Botao,&Li, Hua.(2020).Advanced electrochemical treatment of real biotreated petrochemical wastewater by boron doped diamond anode: performance, kinetics, and degradation mechanism.WATER SCIENCE AND TECHNOLOGY,82(4),773-786.
MLA Li, Hao,et al."Advanced electrochemical treatment of real biotreated petrochemical wastewater by boron doped diamond anode: performance, kinetics, and degradation mechanism".WATER SCIENCE AND TECHNOLOGY 82.4(2020):773-786.
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