Characterization of biofuel production from hydrothermal treatment of hyperaccumulator waste (Pteris vittata L.) in sub- and supercritical water | |
Chen, Jinbo; Li, Songmao | |
刊名 | RSC ADVANCES |
2020 | |
卷号 | 10期号:4页码:2160-2169 |
关键词 | BIO-OIL PRODUCTION BARLEY STRAW THERMOCHEMICAL CONVERSION LIQUEFACTION HTL SEWAGE-SLUDGE BIOMASS TEMPERATURE GASIFICATION LIGNIN FUEL |
DOI | 10.1039/c9ra09410e |
英文摘要 | In this study, hyperaccumulator waste, i.e., Pteris vittata L. was converted into bio-oil, biogas and biochar via sub- and supercritical hydrothermal liquefaction processes. These products were characterized in terms of EI/MS, FTIR, TGA and GC to understand their chemical composition, thermal decomposition, structural properties and high biofuel reactivity. Characterization results revealed that the dominant chemical components in the heavy bio-oil were esters (40.22%), phenols (20.02%), alcohols (10.16%), organic acids (9.07%), nitrogenous compounds (8.83%) and ketones/aldehydes (6.42%), while the light oil was rich with a higher fraction of phenols (54.13%) and nitrogenous compounds (27.04%). Particularly, bio-oils obtained from supercritical conditions contained increased phenolic compounds and reduced oxygenated chemicals such as alcohols, aliphatic acid, ketones and aldehydes, suggesting the improved quality of bio-oil due to the reduction in oxygen contents. Meanwhile, H-2-rich syngas production with the H-2 yield of 38.87% was obtained at 535 degrees C for 20 min, and higher reaction temperature presented a positive influence on H-2 production during Pteris vittata L. liquefaction. Moreover, the remaining biochar product was analyzed to determine whether it could be used as a direct solid fuel or auxiliary fuel. This study provided full exploitation of this feedstock waste in energy and valuable chemical complexes. |
学科主题 | Chemistry |
内容类型 | 期刊论文 |
源URL | [http://ir.nimte.ac.cn/handle/174433/20211] |
专题 | 2020专题 |
作者单位 | Chen, JB (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China. |
推荐引用方式 GB/T 7714 | Chen, Jinbo,Li, Songmao. Characterization of biofuel production from hydrothermal treatment of hyperaccumulator waste (Pteris vittata L.) in sub- and supercritical water[J]. RSC ADVANCES,2020,10(4):2160-2169. |
APA | Chen, Jinbo,&Li, Songmao.(2020).Characterization of biofuel production from hydrothermal treatment of hyperaccumulator waste (Pteris vittata L.) in sub- and supercritical water.RSC ADVANCES,10(4),2160-2169. |
MLA | Chen, Jinbo,et al."Characterization of biofuel production from hydrothermal treatment of hyperaccumulator waste (Pteris vittata L.) in sub- and supercritical water".RSC ADVANCES 10.4(2020):2160-2169. |
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