Comparative Study on the Properties of Epoxy Derived from Aromatic and Heteroaromatic Compounds: The Role of Hydrogen Bonding

doi:10.1021/acs.iecr.9b05904

CORC > 宁波材料技术与工程研究所 > 中国科学院宁波材料技术与工程研究所 > 2020专题

	Comparative Study on the Properties of Epoxy Derived from Aromatic and Heteroaromatic Compounds: The Role of Hydrogen Bonding
	Liu, Yuan; Zhao, Jun; Peng, Yunyan; Luo, Jun; Cao, Lijun; Liu, Xiaoqing
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2020
卷号	59 期号:5 页码:1914-1924
关键词	SURFACE-FREE-ENERGY HOMOGENEOUS CONDITIONS N-BROMOSUCCINIMIDE CURING KINETICS FURAN RESIN TRIPHENYLPHOSPHINE BROMINATION ANHYDRIDE POLYBENZOXAZINE
DOI	10.1021/acs.iecr.9b05904
英文摘要	Epoxy derived from heteroaromatic compounds and its properties are seldom reported. In this work, two model epoxy monomers (EP-B and EP-F) were synthesized from isophthalic acid and 2,5-furandicarboxylic acid. After curing with 4,4-diaminodiphenyl-methane (DDM) in a stoichiometric quantity of 2:1, their properties were comparatively investigated, especially the formation and role of hydrogen bonding in them were identified. Results obtained from differential scanning calorimetry (DSC), dynamic thermomechanical analysis (DMA), fluorescence emission spectra, and static contact angle measurements showed that the cured EP-F/DDM system exhibited unexpected performance in higher glass transition temperature (T-g), fluorescence intensity, and hydrophilicity. And temperature-dependent Fourier transform infrared (FTIR) analysis further confirmed that it was the more hydrogen bonding in the cured EP-F/DDM, involved with the oxygen heteroatoms in the furan ring, which led to its better properties. This work gives us some new insights into the role of electronegative heteroatoms in epoxy resin synthesized from heteroaromatic compounds.
学科主题	Engineering
内容类型	期刊论文
源URL	[http://ir.nimte.ac.cn/handle/174433/20001]
专题	2020专题
作者单位	Liu, XQ (corresponding author), Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China.
推荐引用方式 GB/T 7714	Liu, Yuan,Zhao, Jun,Peng, Yunyan,et al. Comparative Study on the Properties of Epoxy Derived from Aromatic and Heteroaromatic Compounds: The Role of Hydrogen Bonding[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(5):1914-1924.
APA	Liu, Yuan,Zhao, Jun,Peng, Yunyan,Luo, Jun,Cao, Lijun,&Liu, Xiaoqing.(2020).Comparative Study on the Properties of Epoxy Derived from Aromatic and Heteroaromatic Compounds: The Role of Hydrogen Bonding.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(5),1914-1924.
MLA	Liu, Yuan,et al."Comparative Study on the Properties of Epoxy Derived from Aromatic and Heteroaromatic Compounds: The Role of Hydrogen Bonding".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.5(2020):1914-1924.