Capillary Microfluidic-Assisted Surface Structuring
Li, Wei; Sheng, Wenbo; Wegener, Erik; Du, Yunhao; Li, Bin; Zhang, Tao; Jordan, Rainer
刊名ACS MACRO LETTERS
2020
卷号9期号:3页码:328-333
关键词TRANSFER RADICAL POLYMERIZATION BRUSH GROWTH FABRICATION GRADIENTS
DOI10.1021/acsmacrolett.9b00921
英文摘要A facile and universal oxygen-tolerant, capillary microfluidic-derived, controlled radical polymerization for surface structuring (gradient and patterned polymer brushes) is reported. A syringe pump and a filter paper sheet are used as capillary microfluidic to supply the reaction solution (monomer, solvent, and ligand) to a sandwich-shaped setup by placing a flat copper plate onto an ATRP initiator-modified substrate and resulting in gradient polymer brush formation with controlled thickness, steepness, and grafting area, polymers are showing the high chain-end fidelity. Two different polymer brushes (binary polymer brushes) can be simultaneously grown from both ends of the initiator modified substrate by using this method, which can be used to study the interfacial properties of different polymer brushes.
学科主题Polymer Science
内容类型期刊论文
源URL[http://ir.nimte.ac.cn/handle/174433/19867]  
专题2020专题
作者单位1.Zhang, T (corresponding author), Chinese Acad Sci, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China.
2.Jordan, R (corresponding author), Tech Univ Dresden, Fac Chem & Food Chem, Sch Sci, Chair Macromol Chem, D-01069 Dresden, Germany.
3.Zhang, T (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
4.Li, B (corresponding author), Tech Univ Munich, Phys Dept, D-85748 Garching, Germany.
推荐引用方式
GB/T 7714
Li, Wei,Sheng, Wenbo,Wegener, Erik,et al. Capillary Microfluidic-Assisted Surface Structuring[J]. ACS MACRO LETTERS,2020,9(3):328-333.
APA Li, Wei.,Sheng, Wenbo.,Wegener, Erik.,Du, Yunhao.,Li, Bin.,...&Jordan, Rainer.(2020).Capillary Microfluidic-Assisted Surface Structuring.ACS MACRO LETTERS,9(3),328-333.
MLA Li, Wei,et al."Capillary Microfluidic-Assisted Surface Structuring".ACS MACRO LETTERS 9.3(2020):328-333.
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