Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites

doi:10.1016/j.isci.2019.100814

	Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites
	Zheng, Anqing 1,2,3,4,5; Huang, Zhen 2,4,5; Wei, Guoqiang 2,4,5; Zhao, Kun 2,4,5; Jiang, Liqun 2,4,5; Zhao, Zengli 2,4,5; Tian, Yuanyu 1; Li, Haibin 2,4,5
刊名	ISCIENCE
	2020-01-24
卷号	23 期号:1 页码:27
DOI	10.1016/j.isci.2019.100814
通讯作者	Zhao, Zengli(zhaozl@ms.giec.ac.cn) ; Tian, Yuanyu(tianyy1008@126.com)
英文摘要	Selectively breaking the C-O bonds within biomass during catalytic fast pyrolysis (CFP) is desired, but extremely challenging. Herein, we develop a series of metal-oxide nanocomposites composed of W, Mo, Zr, Ti, or Al. It is demonstrated that the nanocomposites of WO3-TiO2-Al2O3 exhibit the highest deoxygenation ability during CFP of lignin, which can compete with the commercial HZSM-5 catalyst. The nanocomposites can selectively cleave the C-O bonds within lignin-derived phenols to form aromatics by direct demethoxylation and subsequent dehydration. Moreover, the nanocomposites can also achieve the selective breaking of the C-O bonds within xylan and cellulose to form furans by dehydration. The Bronsted and Lewis acid sites on the nanocomposites can be responsible for the deoxygenation of lignin and polysaccharides, respectively. This study provides new insights for the rational design of multifunctional catalysts that are capable of simultaneously breaking the C-O bonds within lignin and polysaccharides.
资助项目	National Key R&D Program of China[2017YFE0124200] ; National Natural Science Foundation of China[51776209] ; National Natural Science Foundation of China[51661145011] ; National Natural Science Foundation of China[21406227] ; Natural Science Foundation of Shenzhen[JCYJ20170818164006890] ; Science and Technology Planning Project of Guangdong Province[2015A020215024] ; Youth Innovation Promotion Association, CAS[2018383] ; Pearl River S&T Nova Program of Guangzhou[201806010061]
WOS关键词	SOLID ACID CATALYSTS ; LIGNOCELLULOSIC BIOMASS ; AROMATIC-HYDROCARBONS ; BIO-OIL ; CHEMICAL-STRUCTURE ; FLUIDIZED-BED ; LIGNIN ; MECHANISM ; CELLULOSE ; CONVERSION
WOS研究方向	Science & Technology - Other Topics
语种	英语
出版者	CELL PRESS
WOS记录号	WOS:000508685200065
资助机构	National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Shenzhen ; Science and Technology Planning Project of Guangdong Province ; Youth Innovation Promotion Association, CAS ; Pearl River S&T Nova Program of Guangzhou
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/26352]
专题	中国科学院广州能源研究所
通讯作者	Zhao, Zengli; Tian, Yuanyu
作者单位	1.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Shenzhen Huazhong Univ Sci & Technol, Res Inst, Shenzhen 523000, Peoples R China 4.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Anqing,Huang, Zhen,Wei, Guoqiang,et al. Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites[J]. ISCIENCE,2020,23(1):27.
APA	Zheng, Anqing.,Huang, Zhen.,Wei, Guoqiang.,Zhao, Kun.,Jiang, Liqun.,...&Li, Haibin.(2020).Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites.ISCIENCE,23(1),27.
MLA	Zheng, Anqing,et al."Controlling Deoxygenation Pathways in Catalytic Fast Pyrolysis of Biomass and Its Components by Using Metal-Oxide Nanocomposites".ISCIENCE 23.1(2020):27.