A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel

doi:10.1016/j.apcatb.2019.118114

	A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel
	Li, Ming 1,2,3,4; Fu, Junying 1,2,3; Xing, Shiyou 6; Yang, Lingmei 1,2,3; Zhang, Xufeng 1,2,3; Lv, Pengmei 1,2,3,5; Wang, Zhongming 1,2,3; Yuan, Zhenhong 1,2,3
刊名	APPLIED CATALYSIS B-ENVIRONMENTAL
	2020
卷号	260 页码:14
关键词	Lithium ion exchange Acid sites Metal centres ZSM-5 Jet fuel
ISSN号	0926-3373
DOI	10.1016/j.apcatb.2019.118114
通讯作者	Lv, Pengmei(lvpm@ms.giec.ac.cn)
英文摘要	A series of novel NiO-LiZSM-5 catalysts with variable active sites was prepared to enhance the hydrogenation of waste oils into jet fuel components (C8-C16) by producing more olefins. In the early stage of the reaction, nickel oxide particles, as strong Lewis acid sites, promoted the cracking process of long-chain olefins into propylene and ethylene, which are the precursors of aromatics and iso-paraffins. As the reaction progressed, the nickel oxide was gradually reduced to nickel by H-2 in the system, and the strong Lewis acid sites were transformed into metal centres, which enhanced the hydrogenation performance of the catalyst. The jet fuel components converted from oleic acid by the catalyst could reach 80.42 mol%, which was approximately 10 mol% greater than that of the traditional Ni-ZSM-5 catalyst. Furthermore, four waste oils were efficiently converted into jet fuel by this catalytic system, the most effective content of jet fuel reached 91.7 mol%.
资助项目	Guangdong Special Support Program[2017TX04Z109] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2018A030310078] ; National Natural Science Foundation of China[21576260] ; National Natural Science Foundation of China Youth[51806225] ; National Natural Science Foundation of China Youth[51606201] ; Special Funds of Applied Science and Technology Research of Guangdong Province[2015B020241002]
WOS关键词	DIESEL-RANGE ALKANES ; BIODIESEL PRODUCTION ; FATTY-ACIDS ; OLEIC-ACID ; QUANTITATIVE CONVERSION ; SELECTIVE OXIDATION ; HYDROCARBON FUELS ; CARBON DEPOSITION ; PYROLYSIS OIL ; NONEDIBLE OIL
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000496894300022
资助机构	Guangdong Special Support Program ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China Youth ; Special Funds of Applied Science and Technology Research of Guangdong Province
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/26096]
专题	中国科学院广州能源研究所
通讯作者	Lv, Pengmei
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China 6.Univ Utrecht, Debye Inst Nanomat Sci, Inorgan Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands
推荐引用方式 GB/T 7714	Li, Ming,Fu, Junying,Xing, Shiyou,et al. A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2020,260:14.
APA	Li, Ming.,Fu, Junying.,Xing, Shiyou.,Yang, Lingmei.,Zhang, Xufeng.,...&Yuan, Zhenhong.(2020).A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel.APPLIED CATALYSIS B-ENVIRONMENTAL,260,14.
MLA	Li, Ming,et al."A novel catalyst with variable active sites for the direct hydrogenation of waste oils into jet fuel".APPLIED CATALYSIS B-ENVIRONMENTAL 260(2020):14.