Design and Performance Investigation of a Carbon-Free Pt/Ti Cathode with Low Membrane Degradation Rate for Proton Exchange Membrane Water Electrolyser | |
Shi, Yan1,2,3; Guo, Lili1; Lu, Zhuoxin1,2,3; Wang, Zhida1,2,3; Gan, Yuan1; Guo, Chongqing1,2,3; Tan, Hongyi1,2,3; Yan, Changfeng1,2,3 | |
刊名 | ENERGY TECHNOLOGY |
2019-04-01 | |
卷号 | 7期号:5页码:10 |
关键词 | carbon-free current collectors membrane degradation proton exchange membrane water electrolysis Pt Ti cathodes |
ISSN号 | 2194-4288 |
DOI | 10.1002/ente.201800781 |
通讯作者 | Shi, Yan(shiyan@ms.giec.ac.cn) ; Yan, Changfeng(yancf@ms.giec.ac.cn) |
英文摘要 | In a proton exchange membrane (PEM) water electrolyser, Pt-coated porous titanium plate always acts as the current collector both in the anode and cathode. However, the Pt particles on the Ti current collector cannot take part in the electrochemical reactions and thus lead to a lower utilization of the noble metal. In this work, the Pt-coated Ti current collector is directly used as the cathode in the PEM water electrolyser instead of the conventional Pt/C electrode. To improve the performance, Nafion ionomer is coated on the Pt/Ti electrode to enlarge the electrochemical surface area (ECSA); the ECSA of the Pt/Ti electrode is increased by six times, and the utilization of Pt can be elevated to 45%. The voltage of the electrolyser with the Pt/Ti electrode is only 31mV higher than the conventional Pt/C catalyst layer at 1 A cm(-2). After stability tests, an obvious membrane thinning is observed using Pt/C as the cathode while the membrane of the electrolyser with the ionomer-coated Pt/Ti cathode does not show a significant change in thickness. The F ion emission rate shows the membrane degradation rate is reduced by 15 times compared with the conventional Pt/C cathode. |
资助项目 | DNL Cooperation Fund, CAS[DNL180405] ; National Natural Science Foundation of China[51576201] ; Natural Science Foundation of Guangdong Province[2015A030312007] ; Natural Science Foundation of Guangdong Province[2017A030310539] ; Key Lab of Renewable Energy Foundation of Chinese Academy of Sciences[Y707j81001] |
WOS关键词 | HYDROGEN EVOLUTION REACTION ; PEM FUEL-CELL ; SURFACE-DIFFUSION ; CATALYST LAYER ; ALLOY FORMATION ; H-ADATOMS ; OXYGEN ; IONOMER ; ASSEMBLIES ; ELECTRODES |
WOS研究方向 | Energy & Fuels |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000471344300014 |
资助机构 | DNL Cooperation Fund, CAS ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Key Lab of Renewable Energy Foundation of Chinese Academy of Sciences |
内容类型 | 期刊论文 |
源URL | [http://ir.giec.ac.cn/handle/344007/25260] |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Shi, Yan; Yan, Changfeng |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Key Lab New & Renewable Energy Res & Dev Guangdon, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 3.Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Shi, Yan,Guo, Lili,Lu, Zhuoxin,et al. Design and Performance Investigation of a Carbon-Free Pt/Ti Cathode with Low Membrane Degradation Rate for Proton Exchange Membrane Water Electrolyser[J]. ENERGY TECHNOLOGY,2019,7(5):10. |
APA | Shi, Yan.,Guo, Lili.,Lu, Zhuoxin.,Wang, Zhida.,Gan, Yuan.,...&Yan, Changfeng.(2019).Design and Performance Investigation of a Carbon-Free Pt/Ti Cathode with Low Membrane Degradation Rate for Proton Exchange Membrane Water Electrolyser.ENERGY TECHNOLOGY,7(5),10. |
MLA | Shi, Yan,et al."Design and Performance Investigation of a Carbon-Free Pt/Ti Cathode with Low Membrane Degradation Rate for Proton Exchange Membrane Water Electrolyser".ENERGY TECHNOLOGY 7.5(2019):10. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论