Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts

doi:10.1016/j.apenergy.2017.08.078

	Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts
	Zhang, Xinghua 1; Tang, Wenwu ; Zhang, Qi ; Wang, Tiejun ; Ma, Longlong 1
刊名	APPLIED ENERGY
	2018-10-01
卷号	227 页码:73-79
关键词	Lignin Phenolic compounds Hydrodeoxygenation Ni/SiO2 Hydrocarbon
ISSN号	0306-2619
DOI	10.1016/j.apenergy.2017.08.078
通讯作者	Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn)
英文摘要	Ni-based catalysts supported on gamma-Al2O3 and SiO2 were prepared by impregnation. Catalyst characterization was performed using XRD, NH3-TPD,H-2-TPR and chemisorption. Effects of supports on catalytic performance were tested using the hydrodeoxygenation (HDO) of phenolic compounds as a model reaction. Experiment result shows that single phenolic compounds can be converted via HDO reaction over Ni/SiO2 and Ni/gamma-Al2O3 catalysts at 300 degrees C. The hydrocarbon yields are in the range of 60-90%. The effect of supports on the reaction mechanism was also explored. It is found that hydrogenation of the aromatic ring preferentially occurs over Ni/SiO2 catalyst while the cleavage of C-AR-O bond preferentially occurs over Ni/gamma-Al2O3 catalyst in the HDO of phenol. Compared to Ni/gamma-Al2O3 catalyst, Ni/SiO2 catalyst exhibits better repeatability and higher catalytic activity for hydrocarbon yield when mixed phenolic compounds were used as feedstock in the HDO reaction, and the carbon deposited on the surface of Ni/SiO2 catalyst is lower.
资助项目	National Natural Science Foundation of China - China[51536009] ; National Natural Science Foundation of China - China[51576198] ; National Key Technology R & D Program - China[2015BAD15B06] ; STS program of Chinese Academy of Sciences - China[KFJ-EW-STS-138] ; Science and Technology Planning Project of Guangdong Province - China[2014A01016020] ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China[2015288]
WOS关键词	BIO-OIL ; BIOMASS ; GUAIACOL ; HYDROGENATION ; DECOMPOSITION ; DEGRADATION ; TEMPERATURE ; CHEMICALS ; GASOLINE ; PT/SIO2
WOS研究方向	Energy & Fuels ; Engineering
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000445987200008
资助机构	National Natural Science Foundation of China - China ; National Key Technology R & D Program - China ; STS program of Chinese Academy of Sciences - China ; Science and Technology Planning Project of Guangdong Province - China ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/24006]
专题	中国科学院广州能源研究所
通讯作者	Zhang, Xinghua; Ma, Longlong
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,et al. Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts[J]. APPLIED ENERGY,2018,227:73-79.
APA	Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2018).Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts.APPLIED ENERGY,227,73-79.
MLA	Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts".APPLIED ENERGY 227(2018):73-79.