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Core-Sheath Paraffin-Wax-Loaded Nanofibers by Electrospinning for Heat Storage
Lu, Yuan1,2,4,6; Xiao, Xiudi1,2,6; Zhan, Yongjun1,2,6; Huan, Changmeng1,2,4,6; Qi, Shuai1,2,3,6; Cheng, Haoliang1,2,6; Xu, Gang1,2,5,6
刊名ACS APPLIED MATERIALS & INTERFACES
2018-04-18
卷号10期号:15页码:12759-12767
关键词phase change material paraffin wax electrospinning core-sheath heat storage
ISSN号1944-8244
DOI10.1021/acsami.8b02057
通讯作者Xiao, Xiudi(xiaoxd@ms.giec.ac.cn)
英文摘要Paraffin wax (PW) is widely used for smart thermoregulation materials due to its good thermal performance. However, the leakage and low thermal conductivity of PW hinder its application in the heat storage field. Accordingly, developing effective methods to address these issues is of great importance. In this study, we explored a facile approach to obtain PW-loaded core-sheath structured flexible nanofibers films via coaxial electrospinning technique. The PW as the core layer was successfully encapsulated by the sheath-layer poly (methyl methacrylate). The diameter of the fiber core increased from 395 to 848 run as the core solution speed rate increased from 0.1 to 0.5 mL/h. In addition, it can be seen that higher core solution speed rate could lead to higher PW encapsulation efficiency according to the transmission electron microscopy results. The core-sheath nanofiber films, moreover, possessed the highest latent heat of 58.25 J/g and solidifying enthalpy of -56.49 J/g. In addition, we found that after 200 thermal cycles, there was little change in latent heat, which demonstrated that it is beneficial for the PW-loaded core-sheath structure to overcome the leakage issue and enhance thermal stability properties for the thermoregulation film.
资助项目Major Science and Technology Project of Guangdong Province[2013A011401011] ; Youth Innovation Promotion Association CAS[2017400] ; Special Plan of Guangdong Province[2015TQ01N714] ; Pearl River Star of Science and Technology[2014J2200078] ; Science and Technology Project of Guangdong Province[2014A010106018] ; National Natural Science Foundation of China[51506205] ; Project of Science and Technology Service Network initiative[KFJ-STS-QYZD-010] ; Major Science and Technology Project of Tibet Autonomous Region[ZD20170017]
WOS关键词THERMAL-ENERGY STORAGE ; PHASE-CHANGE MATERIALS ; CARBON NANOTUBES ; CONDUCTIVITY ENHANCEMENT ; ULTRAFINE FIBERS ; SHELL ; ENCAPSULATION ; PERFORMANCE ; FABRICATION ; COMPOSITES
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000430642100067
资助机构Major Science and Technology Project of Guangdong Province ; Youth Innovation Promotion Association CAS ; Special Plan of Guangdong Province ; Pearl River Star of Science and Technology ; Science and Technology Project of Guangdong Province ; National Natural Science Foundation of China ; Project of Science and Technology Service Network initiative ; Major Science and Technology Project of Tibet Autonomous Region
内容类型期刊论文
源URL[http://ir.giec.ac.cn/handle/344007/23247]  
专题中国科学院广州能源研究所
通讯作者Xiao, Xiudi
作者单位1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Tibet New Energy Res & Demonstrat Ctr, Lhasa 850000, Tibet, Peoples R China
6.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Lu, Yuan,Xiao, Xiudi,Zhan, Yongjun,et al. Core-Sheath Paraffin-Wax-Loaded Nanofibers by Electrospinning for Heat Storage[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(15):12759-12767.
APA Lu, Yuan.,Xiao, Xiudi.,Zhan, Yongjun.,Huan, Changmeng.,Qi, Shuai.,...&Xu, Gang.(2018).Core-Sheath Paraffin-Wax-Loaded Nanofibers by Electrospinning for Heat Storage.ACS APPLIED MATERIALS & INTERFACES,10(15),12759-12767.
MLA Lu, Yuan,et al."Core-Sheath Paraffin-Wax-Loaded Nanofibers by Electrospinning for Heat Storage".ACS APPLIED MATERIALS & INTERFACES 10.15(2018):12759-12767.
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