Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst

doi:10.1021/acs.iecr.7b03699

	Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst
	Guo, Haijun 1,3,4,5,6; Zhang, Hairong 1,3,5,6; Zhang, Liquan 1,2,3,5,6; Wang, Can 1,3,5,6; Peng, Fen 1,3,5,6; Huang, Qianlin 1,2,3,5,6; Xiong, Lian 1,3,5,6; Huang, Chao 1,3,5,6; Ouyang, Xinping 4; Chen, Xinde 1,3,5,6
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2018-01-17
卷号	57 期号:2 页码:498-511
ISSN号	0888-5885
DOI	10.1021/acs.iecr.7b03699
通讯作者	Ouyang, Xinping(ceouyang@scut.edu.cn) ; Chen, Xinde(cxd_cxd@hotmail.com)
英文摘要	Acid-activated attapulgite (H+-ATP)-supported NiCoB amorphous alloy catalysts were applied to the selective hydrogenation of furfural (FUR) to furfuryl alcohol (FA). The reduction process between metallic ions impregnated in/on H+-ATP and BH4- is important to modify the textural properties of catalyst, because of the secondary activation of Er-ATP. The enhancement of interaction between H+-ATP and NiCoB particles promotes the dispersion of NiCoB amorphous alloy. Under the optimal conditions (140 degrees C, 3 MPa H-2, 800 rpm, 3.8 wt % of NiCoB active component with respect to FUR), FUR conversion of 91.3%, and FA selectivity of 82.0% were achieved over the best catalyst (20%NiCoB/H+-ATP). Moreover, the catalyst was recycled six times and showed an increase of 3.9% in FUR conversion and 8.2% in FA selectivity, which might be due to the newly generated Co-Ni alloy active site. The low-cost nature of H+-ATP makes the supported NiCoB catalyst a potential catalyst for the industrial production of FA.
资助项目	project of National Natural Science Foundation of China[21406229] ; Project of Jiangsu Province Science and Technology[BE2014101] ; project of Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[Y709jh1001] ; Science and Technology Program of Guangzhou, China[201707010240]
WOS关键词	LIQUID-PHASE HYDROGENATION ; NI-B ; NIB/SIO2 CATALYST ; ROOM-TEMPERATURE ; RECENT PROGRESS ; CU-CATALYSTS ; CO ; PALYGORSKITE ; CONVERSION ; BIOMASS
WOS研究方向	Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000423140100008
资助机构	project of National Natural Science Foundation of China ; Project of Jiangsu Province Science and Technology ; project of Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development ; Science and Technology Program of Guangzhou, China
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/22901]
专题	中国科学院广州能源研究所
通讯作者	Ouyang, Xinping; Chen, Xinde
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China 4.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China 5.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 6.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Guo, Haijun,Zhang, Hairong,Zhang, Liquan,et al. Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(2):498-511.
APA	Guo, Haijun.,Zhang, Hairong.,Zhang, Liquan.,Wang, Can.,Peng, Fen.,...&Qiu, Xueqing.(2018).Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(2),498-511.
MLA	Guo, Haijun,et al."Selective Hydrogenation of Furfural to Furfuryl Alcohol over Acid Activated Attapulgite-Supported NiCoB Amorphous Alloy Catalyst".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.2(2018):498-511.