Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO

doi:10.1016/j.cej.2017.10.092

	Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO
	Dong, Kaijun 1,2,3; Zhang, Jun 1,2,3; Luo, Weimin 1,2,3; Su, Lin 1,2,3; Huang, Zhilin 1,2,3,4
刊名	CHEMICAL ENGINEERING JOURNAL
	2018-02-15
卷号	334 页码:1055-1064
关键词	Hyper-cross-linked polymer Carbohydrates Dehydration 5-Hydroxymethyl furfural
ISSN号	1385-8947
DOI	10.1016/j.cej.2017.10.092
通讯作者	Zhang, Jun(zhangjun@ms.giec.ac.cn)
英文摘要	An acid functionalized porous organic hyper-cross-linked polymer (HCP) derived from benzene monomer was prepared for catalytic dehydration of carbohydrates into 5-hydroxymethyl furfural (HMF) in a DMSO solvent. Systematic characterizations of the HCP catalysts including essential structural properties, sulfur content and acid amount, were identified by XRD, XPS, FESEM, Raman, NH3-TPD, TGA, nitrogen physisorption and elemental analysis. Optimization of reaction parameters such as acid amount, solvent, substrate type, temperature and catalyst dosage, and comparison with reported solid acids were systematically investigated. The results showed that sulfonated HCP materials were highly active in fructose dehydration, which could afford a highest HMF yield of 96.7% at almost 100% fructose conversion in 30 min. Furthermore, the catalyst presented satisfied performance and stability during recycling tests. More importantly, the sulfonated HCP catalysts also exhibited promising activity in hydrolytic reaction, esterification and transesterification for platform chemicals production in biomass transformation.
资助项目	Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B090901012]
WOS关键词	SOLID ACID CATALYSTS ; ION-EXCHANGE-RESIN ; D-FRUCTOSE ; SELECTIVE CONVERSION ; BIODIESEL PRODUCTION ; MESOPOROUS SILICA ; LEVULINIC ACID ; DEHYDRATION ; GLUCOSE ; WATER
WOS研究方向	Engineering
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000418533400104
资助机构	Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/22754]
专题	中国科学院广州能源研究所
通讯作者	Zhang, Jun
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO[J]. CHEMICAL ENGINEERING JOURNAL,2018,334:1055-1064.
APA	Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2018).Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO.CHEMICAL ENGINEERING JOURNAL,334,1055-1064.
MLA	Dong, Kaijun,et al."Catalytic conversion of carbohydrates into 5-hydroxymethyl furfural over sulfonated hyper-cross-linked polymer in DMSO".CHEMICAL ENGINEERING JOURNAL 334(2018):1055-1064.