Cyclonerane sesquiterpenes and an isocoumarin derivative from the marine-alga-endophytic fungus Trichoderma citrinoviride A-WH-20-3
Liu, Xiang-Hong; Hou, Xu-Liang; Song, Yin-Ping; Wang, Bin-Gui; Ji, Nai-Yun
刊名FITOTERAPIA
2020-03
卷号141页码:104469
关键词CYCLOPENTENONE DERIVATIVES SECONDARY METABOLITES CONFIGURATION ELUCIDATION STROMATA
DOI10.1016/j.fitote.2020.104469
产权排序[Liu, Xiang-Hong ; Hou, Xu-Liang ; Song, Yin-Ping ; Wang, Bin-Gui ; Ji, Nai-Yun] Chinese Acad Sci, Ctr Ocean Mega Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China ; [Liu, Xiang-Hong ; Wang, Bin-Gui] Chinese Acad Sci, Lab Marine Biol & Biotechnol, Qingdao Natl Lab Marine Sci & Technol, Key Lab Expt Marine Biol,Inst Oceanol, Qingdao 266071, Peoples R China ; [Liu, Xiang-Hong ; Hou, Xu-Liang] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
文献子类Article
英文摘要Two new cyclonerane sesquiterpenes, (10E)-isocyclonerotriol (1) and (10Z)-isocyclonerotriol (2), and one new isocoumarin derivative, trichophenol A (3), were isolated from Trichoderma citrinoviride A-WH-20-3, an endophyte from the marine red alga Laurencia okamurai. Their structures and relative configurations were assigned by spectroscopic techniques, highlighted by using Sarotti's DP4+ sheet to confirm the cyclopentane ring. The absolute configuration of 1 was established by comparison of experimental and calculated specific rotation data. Compounds 1 and 2 represent the first occurrence of ring-isomerized cycloneranes. Compound 3 is the first 3-phenylisocoumarin derivative from Trichoderma and features inhibition of several marine-derived bacteria and phytoplankton species.
WOS关键词CYCLOPENTENONE DERIVATIVES ; SECONDARY METABOLITES ; CONFIGURATION ; ELUCIDATION ; STROMATA
语种英语
WOS记录号WOS:000518703900012
资助机构Natural Science Foundation for Distinguished Young Scholars of Shandong Province [JQ201712] ; National Natural Science Foundation of ChinaNational Natural Science Foundation of China [31670355] ; Youth Innovation Promotion Association of CAS [2013138] ; Shuangbai Plan of Yantai [2018-3] ; Taishan Scholar Project Special Funding [tsqn201909164]
内容类型期刊论文
源URL[http://ir.yic.ac.cn/handle/133337/25081]  
专题海岸带生物资源高效利用研究与发展中心
烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室
作者单位1.Chinese Acad Sci, Ctr Ocean Mega Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China;
2.Chinese Acad Sci, Lab Marine Biol & Biotechnol, Qingdao Natl Lab Marine Sci & Technol, Key Lab Expt Marine Biol,Inst Oceanol, Qingdao 266071, Peoples R China;
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Liu, Xiang-Hong,Hou, Xu-Liang,Song, Yin-Ping,et al. Cyclonerane sesquiterpenes and an isocoumarin derivative from the marine-alga-endophytic fungus Trichoderma citrinoviride A-WH-20-3[J]. FITOTERAPIA,2020,141:104469.
APA Liu, Xiang-Hong,Hou, Xu-Liang,Song, Yin-Ping,Wang, Bin-Gui,&Ji, Nai-Yun.(2020).Cyclonerane sesquiterpenes and an isocoumarin derivative from the marine-alga-endophytic fungus Trichoderma citrinoviride A-WH-20-3.FITOTERAPIA,141,104469.
MLA Liu, Xiang-Hong,et al."Cyclonerane sesquiterpenes and an isocoumarin derivative from the marine-alga-endophytic fungus Trichoderma citrinoviride A-WH-20-3".FITOTERAPIA 141(2020):104469.
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