An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel
Li, Jinghui3; Qin, Wei1,2,3
刊名MICROCHEMICAL JOURNAL
2020-12-01
卷号159页码:6
关键词Screen-printed potentiometric sensor Three-dimensional porous graphene aerogel Solid contact All-solid-state ion-selective electrode
ISSN号0026-265X
DOI10.1016/j.microc.2020.105453
通讯作者Qin, Wei(wqin@yic.ac.cn)
英文摘要An integrated all-solid-state screen-printed ion-selective potentiometric sensor for the determination of Cu2+ is proposed. The whole-cell potentiometric sensor incorporates a polymeric membrane copper ion-selective electrode (Cu2+-ISE) as an indicator electrode and an Ag/AgCl reference electrode with a polyvinyl butyral reference membrane. The three-dimensional (3D) self-assembled porous graphene aerogel (PGA) can be conveniently and rapidly electrodeposited on the electrode substrate surface. Due to its interior 3D interconnected porous structures, the PGA has a large electrical double layer capacitance and fast charge transfer capability, which make it promising to be used as solid contact for the fabrication of the Cu2+-ISE. The developed potentiometric sensor shows a good Nernstian response over a range from 10(-6) to 10(-3) M with a detection limit of 10(-6.5) M. In addition, the sensor exhibits a stable potential response with the absence of an undesirable water layer at the ion selective membrane/PGA interface.
资助项目National Natural Science Foundation of China[21677172] ; National Key Research and Development Program of China[2016YFC1400700] ; Taishan Scholar Program of Shandong Province[TSPD20181215]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000598326700011
资助机构National Natural Science Foundation of China ; National Key Research and Development Program of China ; Taishan Scholar Program of Shandong Province
内容类型期刊论文
源URL[http://ir.yic.ac.cn/handle/133337/27579]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_近岸生态与环境实验室
通讯作者Qin, Wei
作者单位1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China
2.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266237, Shandong, Peoples R China
3.Chinese Acad Sci, Shandong Key Lab Coastal Environm Proc, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China
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GB/T 7714
Li, Jinghui,Qin, Wei. An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel[J]. MICROCHEMICAL JOURNAL,2020,159:6.
APA Li, Jinghui,&Qin, Wei.(2020).An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel.MICROCHEMICAL JOURNAL,159,6.
MLA Li, Jinghui,et al."An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel".MICROCHEMICAL JOURNAL 159(2020):6.
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