An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel | |
Li, Jinghui3; Qin, Wei1,2,3 | |
刊名 | MICROCHEMICAL JOURNAL |
2020-12-01 | |
卷号 | 159页码:6 |
关键词 | Screen-printed potentiometric sensor Three-dimensional porous graphene aerogel Solid contact All-solid-state ion-selective electrode |
ISSN号 | 0026-265X |
DOI | 10.1016/j.microc.2020.105453 |
通讯作者 | Qin, Wei(wqin@yic.ac.cn) |
英文摘要 | An integrated all-solid-state screen-printed ion-selective potentiometric sensor for the determination of Cu2+ is proposed. The whole-cell potentiometric sensor incorporates a polymeric membrane copper ion-selective electrode (Cu2+-ISE) as an indicator electrode and an Ag/AgCl reference electrode with a polyvinyl butyral reference membrane. The three-dimensional (3D) self-assembled porous graphene aerogel (PGA) can be conveniently and rapidly electrodeposited on the electrode substrate surface. Due to its interior 3D interconnected porous structures, the PGA has a large electrical double layer capacitance and fast charge transfer capability, which make it promising to be used as solid contact for the fabrication of the Cu2+-ISE. The developed potentiometric sensor shows a good Nernstian response over a range from 10(-6) to 10(-3) M with a detection limit of 10(-6.5) M. In addition, the sensor exhibits a stable potential response with the absence of an undesirable water layer at the ion selective membrane/PGA interface. |
资助项目 | National Natural Science Foundation of China[21677172] ; National Key Research and Development Program of China[2016YFC1400700] ; Taishan Scholar Program of Shandong Province[TSPD20181215] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000598326700011 |
资助机构 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Taishan Scholar Program of Shandong Province |
内容类型 | 期刊论文 |
源URL | [http://ir.yic.ac.cn/handle/133337/27579] |
专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 烟台海岸带研究所_近岸生态与环境实验室 |
通讯作者 | Qin, Wei |
作者单位 | 1.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol, Lab Marine Biol & Biotechnol, Qingdao 266237, Shandong, Peoples R China 3.Chinese Acad Sci, Shandong Key Lab Coastal Environm Proc, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC,YICCAS, Yantai 264003, Shandong, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Jinghui,Qin, Wei. An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel[J]. MICROCHEMICAL JOURNAL,2020,159:6. |
APA | Li, Jinghui,&Qin, Wei.(2020).An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel.MICROCHEMICAL JOURNAL,159,6. |
MLA | Li, Jinghui,et al."An integrated all-solid-state screen-printed potentiometric sensor based on a three-dimensional self-assembled graphene aerogel".MICROCHEMICAL JOURNAL 159(2020):6. |
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