A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots
Wang, Yifan1; Yang, Liang2; Liu, Bianhua2; Yu, Shaoming1; Jiang, Changlong2
刊名NEW JOURNAL OF CHEMISTRY
2018-10-07
卷号42期号:19页码:15671-15677
ISSN号1144-0546
DOI10.1039/c8nj03683g
英文摘要

Fluorescent colorimetric test paper has broad prospects for the detection of different environments, medicines and foods by observing the variations of fluorescence brightness and color with the naked eye. Unlike classical pH test papers, however, it is usually limited in qualitative detection by fluorescence brightness and color, and colorimetry-based quantification remains a challenging task. Herein, a novel dual-colored carbon dot (CD) ratiometric fluorescent test paper has been developed for the semi-quantitative and visual assay of mercury ions (Hg2+) by a dose-sensitive color evolution. The blue fluorescence can be sensitively and selectively quenched by Hg2+, while the red fluorescence serves as the internal reference, inducing a distinguishable fluorescence color change from blue to red under illumination by a UV lamp and resulting in the ultrasensitive and visual detection of aqueous Hg2+. The detection limit of this highly sensitive ratiometric probe is as low as 0.14 nM. Moreover, a fluorescent test paper was constructed by printing "ink" onto a piece of filter paper with the probe solution, and a serial color evolution from blue to purple, pink and finally to red with the addition of Hg2+ was displayed, which provides a convenient and simple approach for the visual detection of Hg2+. Meanwhile, the as-prepared fluorescent colorimetric test paper was also successfully applied for the determination of Hg2+ in real water samples.

资助项目National Basic Research Program of China[2015CB932002] ; China-Singapore Joint Project[2015DFG92510] ; Science and Technology Service Network Initiative of Chinese Academy of China[KFJ-SW-STS-172] ; National Natural Science Foundation of China[21371174] ; National Natural Science Foundation of China[21671052]
WOS关键词GRAPHENE QUANTUM DOTS ; LABEL-FREE DETECTION ; RATIOMETRIC FLUORESCENCE ; COPPER IONS ; WASTE-WATER ; NANODOTS ; GLUCOSE ; HYBRID ; GREEN ; NANOPARTICLES
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000447971700018
内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/39965]  
专题合肥物质科学研究院_中科院合肥智能机械研究所
通讯作者Yu, Shaoming; Jiang, Changlong
作者单位1.Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China
2.Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Wang, Yifan,Yang, Liang,Liu, Bianhua,et al. A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots[J]. NEW JOURNAL OF CHEMISTRY,2018,42(19):15671-15677.
APA Wang, Yifan,Yang, Liang,Liu, Bianhua,Yu, Shaoming,&Jiang, Changlong.(2018).A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots.NEW JOURNAL OF CHEMISTRY,42(19),15671-15677.
MLA Wang, Yifan,et al."A colorimetric paper sensor for visual detection of mercury ions constructed with dual-emission carbon dots".NEW JOURNAL OF CHEMISTRY 42.19(2018):15671-15677.
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