Mechanistic insights into sequestration of U(VI) toward magnetic biochar: Batch, XPS and EXAFS techniques | |
Hu, Qingyuan1; Zhu, Yuling1; Hu, Baowei1; Lu, Songhua2; Sheng, Guodong1 | |
刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES
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2018-08-01 | |
卷号 | 70期号:无页码:217-225 |
关键词 | Magnetic biochar Uranium X-ray absorption spectroscopy Sequestration |
ISSN号 | 1001-0742 |
DOI | 10.1016/j.jes.2018.01.013 |
英文摘要 | The magnetic iron oxide (Fe3O4) nanoparticles stabilized on the biochar were synthesized by fast pyrolysis of Fe(II)-loaded hydrophyte biomass under N2 conditions. The batch experiments showed that magnetic biochar presented a large removal capacity (54.35 mg/g) at pH 3.0 and 293 K. The reductive co-precipitation of U(VI) to U(IV) by magnetic biochar was demonstrated according to X-ray diffraction, X-ray photoelectron spectroscopy and X-ray absorption near edge structure analysis. According to extendedX-ray absorption fine structure analysis, the occurrence of U-Fe and U-U shells indicated that high effective removal of uranium was primarily inner-sphere coordination and then reductive co-precipitation at low pH. These observations provided the further understanding of uranium removal bymagnetic materials in environmental remediation. (c) 2018 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. |
资助项目 | National Natural Science Foundation of China[21207092] ; National Natural Science Foundation of China[21577093] ; Science and Technology Project of Shaoxing[2014B70041] |
WOS关键词 | ENHANCED SEQUESTRATION ; SORPTION MECHANISMS ; IRON NANOPARTICLES ; BACILLUS-SUBTILIS ; CRYSTAL-STRUCTURE ; AQUEOUS-SOLUTION ; FACILE SYNTHESIS ; GRAPHENE OXIDES ; HEAVY-METALS ; U-VI |
WOS研究方向 | Environmental Sciences & Ecology |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000457080600001 |
资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing ; Science and Technology Project of Shaoxing |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/41460] ![]() |
专题 | 合肥物质科学研究院_中科院等离子体物理研究所 |
通讯作者 | Hu, Baowei; Sheng, Guodong |
作者单位 | 1.Shaoxing Univ, Coll Chem & Chem Engn, Coll Life Sci, Shaoxing 312000, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Hu, Qingyuan,Zhu, Yuling,Hu, Baowei,et al. Mechanistic insights into sequestration of U(VI) toward magnetic biochar: Batch, XPS and EXAFS techniques[J]. JOURNAL OF ENVIRONMENTAL SCIENCES,2018,70(无):217-225. |
APA | Hu, Qingyuan,Zhu, Yuling,Hu, Baowei,Lu, Songhua,&Sheng, Guodong.(2018).Mechanistic insights into sequestration of U(VI) toward magnetic biochar: Batch, XPS and EXAFS techniques.JOURNAL OF ENVIRONMENTAL SCIENCES,70(无),217-225. |
MLA | Hu, Qingyuan,et al."Mechanistic insights into sequestration of U(VI) toward magnetic biochar: Batch, XPS and EXAFS techniques".JOURNAL OF ENVIRONMENTAL SCIENCES 70.无(2018):217-225. |
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