Strontium and calcium ion adsorption by molecularly imprinted hybrid gel
Li, Quan; Liu, Haining; Qing, Binju; Ye, Xiushen; Wu, Zhijian; Guo, Min
刊名CHEMICAL ENGINEERING JOURNAL
2010
卷号157期号:2-3页码:401-407
ISSN号1385-8947
英文摘要The adsorption of strontium and calcium ions by strontium ion-imprinted hybrid gel derived from bis(trimethoxysilylpropyl)amine (TSPA) was comparatively studied. The effects of initial solution pH, ionic strength, initial metal ion concentration, and temperature on the equilibrium adsorption amount and the separation factor between strontium and calcium ions were comprehensively investigated. In description of the adsorption kinetics, the pseudo second-order model was found to be more suitable than the pseudo first-order model. In general, the equilibrium adsorption amount of both Sr(2+) and Ca(2+) ions was found to increase with the increase in both the initial metal ion concentration and pH, but not to be so sensitive to ionic strength and temperature. The separation of Sr(2+) and Ca(2+) ions could rely on the difference in adsorption kinetics, because Sr(2+) ions were found to adsorb more rapidly than Ca(2+) ions at the early adsorption stage. (C) 2009 Elsevier B.V. All rights reserved. The adsorption of strontium and calcium ions by strontium ion-imprinted hybrid gel derived from bis(trimethoxysilylpropyl)amine (TSPA) was comparatively studied. The effects of initial solution pH, ionic strength, initial metal ion concentration, and temperature on the equilibrium adsorption amount and the separation factor between strontium and calcium ions were comprehensively investigated. In description of the adsorption kinetics, the pseudo second-order model was found to be more suitable than the pseudo first-order model. In general, the equilibrium adsorption amount of both Sr(2+) and Ca(2+) ions was found to increase with the increase in both the initial metal ion concentration and pH, but not to be so sensitive to ionic strength and temperature. The separation of Sr(2+) and Ca(2+) ions could rely on the difference in adsorption kinetics, because Sr(2+) ions were found to adsorb more rapidly than Ca(2+) ions at the early adsorption stage. (C) 2009 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
公开日期2013-09-11
内容类型期刊论文
源URL[http://ir.isl.ac.cn/handle/363002/1929]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
青海盐湖研究所_盐湖资源与化学实验室
推荐引用方式
GB/T 7714
Li, Quan,Liu, Haining,Qing, Binju,et al. Strontium and calcium ion adsorption by molecularly imprinted hybrid gel[J]. CHEMICAL ENGINEERING JOURNAL,2010,157(2-3):401-407.
APA Li, Quan,Liu, Haining,Qing, Binju,Ye, Xiushen,Wu, Zhijian,&Guo, Min.(2010).Strontium and calcium ion adsorption by molecularly imprinted hybrid gel.CHEMICAL ENGINEERING JOURNAL,157(2-3),401-407.
MLA Li, Quan,et al."Strontium and calcium ion adsorption by molecularly imprinted hybrid gel".CHEMICAL ENGINEERING JOURNAL 157.2-3(2010):401-407.
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