On-Line Monitoring and Analysis Method of Three-Dimensional Fluorescence Spectrum in Urban Domestic Sewage Treatment Process | |
Yang Jin-qiang1,3,4; Zhao Nan-jing1,4; Yin Gao-fang1,4; Yu Zhi-min3; Gan Ting-ting1,4; Wang Xiang1,2,4; Chen Min1,2,4; Feng Chun1,2,4 | |
刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS |
2020-07-01 | |
卷号 | 40 |
关键词 | Municipal sewage Three-dimensional fluorescence spectrum Principal component analysis Dissolved organic matter |
ISSN号 | 1000-0593 |
DOI | 10.3964/j.issn.1000-0593(2020)07-1993-05 |
通讯作者 | Zhao Nan-jing(njzhao@aiofm.ac.cn) |
英文摘要 | Three dimensional fluorescence spectrum (3D EEMs) and principal component analysis (PCA) were used. The threedimensional fluorescence spectrum of urban sewage was divided into four spectral regions : aromatic proteins, microbial metabolites, humic acids and fulvic acids. Determine the regional principal component contribution rate of the lambda lambda. Calculate the value of the first principal component area of each area, to establish it with water chemical oxygen demand (COD) and total nitrogen (TN), studies the urban sewage treatment effect rapid analysis and evaluation method. The results show that the urban sewage fluorescent material is mainly composed of aromaticity protein material, microbial metabolites, humic acid and fulvic acid material, regional fluorescent distribution is different, the material in the process of sewage treatment aromaticity protein material area spectral changes obviously, and the microorganism metabolites humic acid and fulvic acid material area spectral changes smaller, Spectral regions the value of the first principal component area and water body has a good correlation between COD and TN, aromaticity of protein material spectrum coefficient of the value of the first principal component areas related to the COD reached 97. 63% aromaticity protein material and the sum of the value of the first principal component area microbial metabolites and humic acid and fulvic acid material ratio of the sum of the value of the first principal component area (Y-p/Y-f) and TN correlation coefficient reached 94. 02%. By combining the three dimensional fluorescence spectrum of water with the principal component analysis method, the dimensionless extraction of fluorescence spectrum information of each process of sewage treatment is realized, the overlapping of fluorescence peaks and redundancy of spectral information of each substance are avoided. Through the spectral characteristics of each substance in the water, the spectrum is divided into different material regions, the first principal component region value of each region is obtained, which improves the accuracy of substance identification and effectively solves the problem of spectral information identification of each substance. By using the correlation analysis of the first principal component area value of aromatic protein spectrum and Y-p/Y-f and the conventional water quality indexes COD and TN, it provides a real-time and effective method for monitoring the quality of domestic sewage and solves the problem that the sewage treatment process is difficult to accurately monitor in real time. Therefore, the three-dimensional fluorescence spectrum combined with principal component analysis method can be used for fast discrimination of urban domestic sewage treatment process, providing a new fast on-line monitoring and analysis method for water quality monitoring, process optimization and treatment effect evaluation in the sewage treatment process. |
WOS关键词 | DISSOLVED ORGANIC-MATTER ; EXCITATION ; ABSORPTION ; UV |
WOS研究方向 | Spectroscopy |
语种 | 英语 |
出版者 | OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS |
WOS记录号 | WOS:000556010000001 |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/70735] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Zhao Nan-jing |
作者单位 | 1.Key Lab Opt Monitoring Technol Environm, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Hefei Univ, Dept Biol & Environm Engn, Hefei 230601, Peoples R China 4.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Yang Jin-qiang,Zhao Nan-jing,Yin Gao-fang,et al. On-Line Monitoring and Analysis Method of Three-Dimensional Fluorescence Spectrum in Urban Domestic Sewage Treatment Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2020,40. |
APA | Yang Jin-qiang.,Zhao Nan-jing.,Yin Gao-fang.,Yu Zhi-min.,Gan Ting-ting.,...&Feng Chun.(2020).On-Line Monitoring and Analysis Method of Three-Dimensional Fluorescence Spectrum in Urban Domestic Sewage Treatment Process.SPECTROSCOPY AND SPECTRAL ANALYSIS,40. |
MLA | Yang Jin-qiang,et al."On-Line Monitoring and Analysis Method of Three-Dimensional Fluorescence Spectrum in Urban Domestic Sewage Treatment Process".SPECTROSCOPY AND SPECTRAL ANALYSIS 40(2020). |
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