Amide-Functionalized Ionic Liquids As Curing Agents for Epoxy Resin: Preparation, Characterization, and Curing Behaviors with TDE-85 | |
Liu, Long1,3; Gao, Sheng3,4; Jiang, Zhiyi2,3; Zhang, Yanqiang3; Gui, Dayong4; Zhang, Suojiang3 | |
刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH |
2019-08-07 | |
卷号 | 58期号:31页码:14088-14097 |
ISSN号 | 0888-5885 |
DOI | 10.1021/acs.iecr.9b01888 |
英文摘要 | A series of amide-functionalized ionic liquids (ILs), e.g., 1-R-3-(2-amino-2-oxoethyl)-imidazolium (R = -vinyl,-methyl-butyl) cations combined with Cl-, N(CN)2(-), or NTf2- anions, were synthesized and fully characterized as curing agent for diglycidy1-4,5-epoxy-cyclohexane-1,2-dicarboxylate (TDE-85). Studies of curing behaviors showed that lLs with N(CN)(2)(-) anions exhibit moderate curing conditions. As to thermosets of TDE-85 cured by these curing agents, their tensile strength (95.1-111.7 MPa) and elongation at break (2.69 to 4.20%) are significantly improved compared with the traditional curing systems of DDS/TDE-85 (DDS, 4,4'-diamino diphenyl sulphone). These thermosets also exhibit good thermal mechanical properties with the glass transition temperature (T-g) > 200 degrees C and thermal degradation temperature (T-d) > 300 degrees C. The possible mechanisms of curing reactions were analyzed by using IR, and results indicated that curing reactions of TDE-85 with amide-functionalized ionic liquids may include three steps, -NH2 groups reacted with oxirane at lower temperatures, and then the anions further participated in the reaction to strengthen the cross-linking networks. This study provides informative guidelines for designing new curing agents. |
资助项目 | National Natural Science Foundation of China[21676281] ; National Natural Science Foundation of China[21576270] ; National Natural Science Foundation of China[21878278] ; Beijing Natural Science Foundation[2192054] ; Natural Science Foundation of Guangdong Province of China[2017A030313322] |
WOS关键词 | MECHANICAL-PROPERTIES ; STRUCTURAL CHARACTERISTICS ; KINETICS ; POLYMERIZATION ; COMPOSITES ; SALTS ; DDS |
WOS研究方向 | Engineering |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000480496100028 |
资助机构 | National Natural Science Foundation of China ; Beijing Natural Science Foundation ; Natural Science Foundation of Guangdong Province of China |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/30610] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Liu, Long; Gui, Dayong; Zhang, Suojiang |
作者单位 | 1.Zhongke Langfang Inst Proc Engn, Langfang 065001, Peoples R China 2.China Univ Petr, Sch Chem Engn & Environm, Beijing 102249, Peoples R China 3.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China 4.Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518055, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Long,Gao, Sheng,Jiang, Zhiyi,et al. Amide-Functionalized Ionic Liquids As Curing Agents for Epoxy Resin: Preparation, Characterization, and Curing Behaviors with TDE-85[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(31):14088-14097. |
APA | Liu, Long,Gao, Sheng,Jiang, Zhiyi,Zhang, Yanqiang,Gui, Dayong,&Zhang, Suojiang.(2019).Amide-Functionalized Ionic Liquids As Curing Agents for Epoxy Resin: Preparation, Characterization, and Curing Behaviors with TDE-85.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(31),14088-14097. |
MLA | Liu, Long,et al."Amide-Functionalized Ionic Liquids As Curing Agents for Epoxy Resin: Preparation, Characterization, and Curing Behaviors with TDE-85".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.31(2019):14088-14097. |
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