In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution

doi:10.1007/s11814-019-0305-z

	In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution
	Wang, Ze 1,2; Fu, Zhaolin 1,3; Lin, Weigang 1,2; Li, Songgeng 1,2; Song, Wenli 1,2
刊名	KOREAN JOURNAL OF CHEMICAL ENGINEERING
	2019-08-01
卷号	36 期号:8 页码:1235-1242
关键词	Furfural 2-Methylfuran Hydrogen Donor Methanol In-situ Hydrodeoxygenation
ISSN号	0256-1115
DOI	10.1007/s11814-019-0305-z
英文摘要	In-situ hydrodeoxygenation of furfural as a representative component in bio-oil was investigated in aqueous solution over supported Ni catalysts, for preparing furans as an antiknock additive. The addition of methanol, ethanol, or isopropanol was found inhibitive to coke formation at 220 degrees C. When using methanol as the hydrogen donor and coke inhibitor, the support in mesoporous structure with moderate acidity was more favorable to the conversion of furfural and to the formation of furans. An increased loading amount of Ni facilitated the generation of deep hydrogenated products. The conversion of furfural could hardly be changed under different methanol to water ratios, while the product distribution varied remarkably. Under optimized conditions, the summary yield of furan and 2-methylfuran reached to above 85%. On the basis of optimized reaction conditions, the in-situ hydrodeoxygenation of an eight-component synthetic bio-oil was tested, and the results verified the adaptability of the method for conversion of bio-oil.
资助项目	National Natural Science Foundation of China[51476180] ; National Key R&D Program of China[2018YFB0605000]
WOS关键词	PYROLYSIS BIO-OIL ; HYDROGENATION ; BIOMASS ; HYDROTREATMENT ; BIOFUELS ; METHANOL ; PHENOL ; CONVERSION ; REDUCTION
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	KOREAN INSTITUTE CHEMICAL ENGINEERS
WOS记录号	WOS:000477989100003
资助机构	National Natural Science Foundation of China ; National Key R&D Program of China
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/30369]
专题	中国科学院过程工程研究所
通讯作者	Wang, Ze
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100190, Peoples R China 3.Sinopec Res Inst Petr Proc, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Wang, Ze,Fu, Zhaolin,Lin, Weigang,et al. In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2019,36(8):1235-1242.
APA	Wang, Ze,Fu, Zhaolin,Lin, Weigang,Li, Songgeng,&Song, Wenli.(2019).In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution.KOREAN JOURNAL OF CHEMICAL ENGINEERING,36(8),1235-1242.
MLA	Wang, Ze,et al."In-situ hydrodeoxygenation of furfural to furans over supported Ni catalysts in aqueous solution".KOREAN JOURNAL OF CHEMICAL ENGINEERING 36.8(2019):1235-1242.