Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency

doi:10.1002/advs.201901679

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency
	Wang, XF (Wang, Xuefei)[ 1,2 ]; Zhang, FF (Zhang, Fangfang)[ 1 ]; Gao, L (Gao, Le)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
刊名	ADVANCED SCIENCE
	2019
卷号	6 期号:22 页码:1-7
关键词	borates crystal growth habits KBBF family nonlinear optical materials second harmonic generation
ISSN号	2198-3844
DOI	10.1002/advs.201901679
英文摘要	The conflict between beneficial layered structure for performances and layered growth habits in KBe2BO3F2 (KBBF) always restricts its practical applications. A beryllium-free KBBF family member, Zn2BO3(OH), is explored to feature the same topological layer with KBBF by replacing [BeO3F](5-) with [ZnO3(OH)](5-) and excellent UV performances. It exhibits a second harmonic generation response of about 1.5 x KH2PO4 with the UV cutoff edge of 204 nm. The birefringence of Zn2BO3(OH) in the visible region is about 0.067, which is larger than those of commercial UV crystals LiB3O5, CsB3O5, and CsLiB6O10. Additionally, it has excellent thermal and water-resistant stabilities. Owing to the removal of interlayer cations, Zn2BO3(OH) shows better growth habits than KBBF while achieving the balance between beneficial layered structure and layer tendency.
WOS记录号	WOS:000486721000001
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/7213]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
通讯作者	Pan, SL (Pan, Shilie)[ 1 ]
作者单位	1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environme, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Wang, XF ,Zhang, FF ,Gao, L ,et al. Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency[J]. ADVANCED SCIENCE,2019,6(22):1-7.
APA	Wang, XF ,Zhang, FF ,Gao, L ,Yang, ZH ,&Pan, SL .(2019).Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency.ADVANCED SCIENCE,6(22),1-7.
MLA	Wang, XF ,et al."Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency".ADVANCED SCIENCE 6.22(2019):1-7.