FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage

doi:10.1016/j.tetlet.2014.12.146

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	FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage
	Wang, Sinan 2,3,5; Yu, Yang 2,3; Chen, Xuyun 2,3; Zhu, Haipan 1; Du, Peile 1; Liu, Guohua 1; Lou, Liguang5 ; Li, Hao 2,3; Wang, Wei 2,3,4
刊名	TETRAHEDRON LETTERS
	2015-06-03
卷号	56 期号:23 页码:3093-3096
关键词	FeCl3 Acylation 1,3-Diketones C-C bond cleavage
ISSN号	0040-4039
DOI	10.1016/j.tetlet.2014.12.146
文献子类	Article
英文摘要	We describe a novel FeCl3 catalyzed selective acylation of amines involving the C-C bond cleavage of simple 1,3-diketones. The process proceeds efficiently under a neat condition to give structurally diverse amides. Notably, the acylation process displays high selectivity toward amines over hydroxyl functionality. Traditionally difficult aromatic amines and sterically demanding disubstituted amines can engage in the process with high efficiency. (C) 2015 Elsevier Ltd. All rights reserved.
WOS关键词	STAUDINGER LIGATION ; AMIDE SYNTHESIS ; OXIDATIVE AMIDATION ; PEPTIDE-SYNTHESIS ; CARBOXYLIC-ACIDS ; CARBON ; ACTIVATION ; CHEMISTRY ; ALDEHYDES ; CYCLOPROPANES
WOS研究方向	Chemistry
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000356544800028
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/276497]
专题	药理学第一研究室
通讯作者	Li, Hao
作者单位	1.Shanghai Normal Univ, Minist Educ, Key Lab Resource Chem, Shanghai 200234, Peoples R China; 2.E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab New Drug Design, Shanghai 200237, Peoples R China; 3.E China Univ Sci & Technol, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China; 4.Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA 5.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China;
推荐引用方式 GB/T 7714	Wang, Sinan,Yu, Yang,Chen, Xuyun,et al. FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage[J]. TETRAHEDRON LETTERS,2015,56(23):3093-3096.
APA	Wang, Sinan.,Yu, Yang.,Chen, Xuyun.,Zhu, Haipan.,Du, Peile.,...&Wang, Wei.(2015).FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage.TETRAHEDRON LETTERS,56(23),3093-3096.
MLA	Wang, Sinan,et al."FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage".TETRAHEDRON LETTERS 56.23(2015):3093-3096.