Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source

doi:10.1021/acs.orglett.6b03111

	Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source
	Ni, Jiabin 1,2,3; Li, Jie 1,2,4; Fan, Zhoulong 1,2,3; Zhang, Ao1,2,3,4
刊名	ORGANIC LETTERS
	2016-11-18
卷号	18 期号:22 页码:5960-5963
ISSN号	1523-7060
DOI	10.1021/acs.orglett.6b03111
文献子类	Article
英文摘要	A novel and efficient approach for the C(sp(2))-H bond carbonylation of benzamides has been developed using stable and inexpensive Co(OAc)(2).4H(2)O as the catalyst and the commercially available and easily handling azodicarboxylates as the nontoxic carbonyl source. A broad range of substrates bearing diverse functional groups were tolerated. This is the first example where cobalt-catalyzed C(sp(2))-H bond carbonylation occurs with azodicarboxylate as the carbonyl source.
资助项目	Chinese NSF[81430080] ; Chinese NSF[81373277] ; Major State Basic Research Development Program[2015CB910603] ; Program of Shanghai Subject Chief Scientist[16XD1404600]
WOS关键词	C-H BOND ; DIETHYL AZODICARBOXYLATE ; ROOM-TEMPERATURE ; TERMINAL ALKYNES ; ACTIVATION ; AMIDES ; FUNCTIONALIZATION ; ANNULATION ; AMINATION ; ACCESS
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000388428600048
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/275805]
专题	药物化学研究室
通讯作者	Zhang, Ao
作者单位	1.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Synthet Organ & Med Chem Lab, Shanghai 201203, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 4.ShanghaiTech Univ, Shanghai 20120, Peoples R China
推荐引用方式 GB/T 7714	Ni, Jiabin,Li, Jie,Fan, Zhoulong,et al. Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source[J]. ORGANIC LETTERS,2016,18(22):5960-5963.
APA	Ni, Jiabin,Li, Jie,Fan, Zhoulong,&Zhang, Ao.(2016).Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source.ORGANIC LETTERS,18(22),5960-5963.
MLA	Ni, Jiabin,et al."Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source".ORGANIC LETTERS 18.22(2016):5960-5963.