Experimental and theoretical studies on rhodium-catalyzed direct C-H benzoxylation reaction

doi:10.1016/j.tetlet.2018.04.034

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	Experimental and theoretical studies on rhodium-catalyzed direct C-H benzoxylation reaction
	Jin, Chen 2,3,4; Wang, Guimin 1,5; Yang, Xueyan 3,4; Zhu, Weiliang1,5 ; Yang, Yaxi1,2
刊名	TETRAHEDRON LETTERS
	2018-05-23
卷号	59 期号:21 页码:2042-2045
关键词	Rh(III)-catalyzed C-H benzoxylation DFT calculations
ISSN号	0040-4039
DOI	10.1016/j.tetlet.2018.04.034
文献子类	Article
英文摘要	An efficient Rh(III)-catalyzed, chelation assisted C-H benzoxylation reaction has been developed, releasing H2O as the single byproduct. The reaction proceeded under mild conditions, with controllable mono- and dioxygenation selectivity, thus providing a good complement to previous C-H oxygenation reactions. DFT calculations support that a nucleophilic addition pathway is most likely involved in the current reaction system. (C) 2018 Published by Elsevier Ltd.
资助项目	Youth innovation promotion association of the Chinese Academy of Sciences[2017333]
WOS关键词	OXIDATIVE FUNCTIONALIZATION ; BOND FORMATION ; HYDROXYLATION ; ACETOXYLATION ; AMIDATION ; AMINATION ; AZIDES ; OXYGENATION ; ACTIVATION ; COMPLEXES
WOS研究方向	Chemistry
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000432100700015
内容类型	期刊论文
源URL	[http://119.78.100.183/handle/2S10ELR8/279749]
专题	药物发现与设计中心药物化学研究室
通讯作者	Yang, Xueyan; Zhu, Weiliang; Yang, Yaxi
作者单位	1.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Materia Med, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China; 3.East China Univ Sci & Technol, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China; 4.East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China; 5.Chinese Acad Sci, Drug Discovery & Design Ctr, Shanghai Inst Materia Med, Shanghai 201203, Peoples R China;
推荐引用方式 GB/T 7714	Jin, Chen,Wang, Guimin,Yang, Xueyan,et al. Experimental and theoretical studies on rhodium-catalyzed direct C-H benzoxylation reaction[J]. TETRAHEDRON LETTERS,2018,59(21):2042-2045.
APA	Jin, Chen,Wang, Guimin,Yang, Xueyan,Zhu, Weiliang,&Yang, Yaxi.(2018).Experimental and theoretical studies on rhodium-catalyzed direct C-H benzoxylation reaction.TETRAHEDRON LETTERS,59(21),2042-2045.
MLA	Jin, Chen,et al."Experimental and theoretical studies on rhodium-catalyzed direct C-H benzoxylation reaction".TETRAHEDRON LETTERS 59.21(2018):2042-2045.