Synthesis of Arylvinyl-Substituted Fulleropyrrolidines: Novel Reaction of [60]Fullerene with Cinnamaldehydes and Amines

doi:10.1002/slct.201900643

	Synthesis of Arylvinyl-Substituted Fulleropyrrolidines: Novel Reaction of [60]Fullerene with Cinnamaldehydes and Amines
	Ma, Wan 1; Zhang, Duo 1; Wang, Hui-Juan 3; Li, Fa-Bao 1; Liu, Li 1; Liu, Xu-Feng 1; Liu, Chao-Yang 3; Asiri, Abdullah M.2; Alamry, Khalid A.2
刊名	CHEMISTRYSELECT
	2019-05-15
卷号	4 期号:18 页码:5240-5245
关键词	Amines Cinnamaldehydes [60]Fullerene Fulleropyrrolidines High stereoselectivity
ISSN号	2365-6549
DOI	10.1002/slct.201900643
英文摘要	A simple one-step reaction of [60]fullerene with cinnamaldehydes and primary/secondary amines without the addition of any inorganic salts afforded rare arylvinyl-substituted fulleropyrrolidines in moderate to good yields with high stereoselectivity. Secondary amines produced N-alkyl-2/5-arylvinyl fulleropyrrolidines with a preference of trans isomers as major products, while primary amines exclusively gave 2-aryl-5-arylvinyl fulleropyrrolidines as cis isomers. A plausible formation mechanism for fulleropyrrolidines was proposed to elucidate the above reaction process.
资助项目	National Natural Science Foundation of China[21102041] ; National Natural Science Foundation of China[21671061] ; National Natural Science Foundation of China[11575287] ; Scientific Research Foundation of Education Commission of Hubei Province[D20161007] ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province[201710512044] ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province[201810512046] ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology)[SYSJJ2019-10]
WOS关键词	ONE-STEP REACTION ; MEDIATED SYNTHESIS ; FULLERENE DERIVATIVES ; AROMATIC-ALDEHYDES ; ADDITION-REACTIONS ; CHIRAL FULLERENES ; AZOMETHINE YLIDES ; C-60 ; FUNCTIONALIZATION ; AMINOMETHYLATION
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000471813000007
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) ; Open Project of State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/14541]
专题	中国科学院武汉物理与数学研究所
通讯作者	Li, Fa-Bao; Liu, Chao-Yang
作者单位	1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Che Mat, Key Lab Synth & Applicat Organ Funct Mol,Sch Chem, Minist Educ,Key Lab Green Preparat & Applicat Fun, Wuhan 430062, Hubei, Peoples R China 2.King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia 3.Chinese Acad Sci, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Ma, Wan,Zhang, Duo,Wang, Hui-Juan,et al. Synthesis of Arylvinyl-Substituted Fulleropyrrolidines: Novel Reaction of [60]Fullerene with Cinnamaldehydes and Amines[J]. CHEMISTRYSELECT,2019,4(18):5240-5245.
APA	Ma, Wan.,Zhang, Duo.,Wang, Hui-Juan.,Li, Fa-Bao.,Liu, Li.,...&Alamry, Khalid A..(2019).Synthesis of Arylvinyl-Substituted Fulleropyrrolidines: Novel Reaction of [60]Fullerene with Cinnamaldehydes and Amines.CHEMISTRYSELECT,4(18),5240-5245.
MLA	Ma, Wan,et al."Synthesis of Arylvinyl-Substituted Fulleropyrrolidines: Novel Reaction of [60]Fullerene with Cinnamaldehydes and Amines".CHEMISTRYSELECT 4.18(2019):5240-5245.