C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride

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	C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride
	Lu EL(陆而立) ; Chen YF(陈耀峰) ; Zhou JL(周吉亮) ; Leng XB(冷雪冰)
刊名	Organometallics
	2012
卷号	31 期号:12 页码:4574-4578
ISSN号	0276-7333
其他题名	钇氢化物参与的氧膦C-P及C-H键断裂反应
通讯作者	陈耀峰
英文摘要	Reactions of the yttrium anilido hydride [LY(NH(DIPP))(mu-H)](2) (1; L = [MeC(N(DIPP))CHC(Me)(NCH2CH2NMe2)]-, DIPP = (2),6-(Pr2C6H3)-Pr-i)) with three phosphine oxides and two phosphine sulfides are reported. The reaction of 1 with Ph3P=O gives C P bond cleavage and an yttrium anilido phosphinoyl complex, while those with R2MeP=O (R = Me, Ph) result in C H bond cleavage and two yttrium anilido alkyl complexes. 1 also reacted with R3P=S (R = Me, Ph), which demonstrated P S bond cleavage via hydride-based reduction and gave an yttrium anilido sulfide.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/om300369f
语种	英语
WOS记录号	WOS:000305588000024
公开日期	2013-08-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/27959]
专题	上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Lu EL,Chen YF,Zhou JL,et al. C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride[J]. Organometallics,2012,31(12):4574-4578.
APA	陆而立,陈耀峰,周吉亮,&冷雪冰.(2012).C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride.Organometallics,31(12),4574-4578.
MLA	陆而立,et al."C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride".Organometallics 31.12(2012):4574-4578.