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	Antiferromagnetism in two-dimensional polyradical nanosheets
	Yang, Yang1; Liu, Caixing1,2; Xu, Xueli1,2; Meng, Zhi1,2; Tong, Wei1; Ma, Zongwei1; Zhou, Chun1; Sun, Yuping1,3; Sheng, Zhigao1
刊名	POLYMER CHEMISTRY
	2018-12-14
卷号	9期号:46页码:6
ISSN号	1759-9954
DOI	10.1039/c8py01287c
通讯作者	Sheng, Zhigao(zhigaosheng@hmfl.ac.cn)
英文摘要	Two-dimensional (2D) organic magnetic materials have great value for research and applications in spintronics. However, unlike the diverse inorganic materials, finding 2D organic magnetic materials is still a major challenge. In this work, freestanding 2D organic magnetic polyradical (OMP) nanosheets were successfully synthesized using the polymerization of tris(2,3,5,6-tetrachloro-4-ethynylphenyl)methyl radicals at a liquid/liquid interface. The OMP obtained has a 2D sheet-like morphology and possesses triarylmethyl radicals after polymerization, which can act as spin centers. With the magnetic exchange coupling between radicals, the OMP shows an antiferromagnetic behavior with a Neel temperature of 42.5 K. Besides the OMP, this discovery also provides a route for synthesis of other potential antiferromagnetic 2D organic materials, which can act as essential building blocks in 2D organic spintronic devices.
资助项目	National Key R&D Program of China[2017YFA0303603] ; National Key R&D Program of China[2016YFA0401803] ; National Natural Science Foundation of China[U1532155] ; National Natural Science Foundation of China[11574316] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-SLH011] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2016FXCX002] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2016HSC-IU006] ; Instrument Developing Project of the CAS[YZ201423] ; China Postdoctoral Science Foundation[2017M622033] ; One Thousand Youth Talents Program of China
WOS关键词	POLYCHLOROTRIPHENYLMETHYL RADICALS ; FERROMAGNETISM ; MAGNET
WOS研究方向	Polymer Science
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000451658100002
资助机构	National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; Instrument Developing Project of the CAS ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China ; One Thousand Youth Talents Program of China
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/40500]
专题	合肥物质科学研究院_中科院强磁场科学中心
通讯作者	Sheng, Zhigao
作者单位	1.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Yang, Yang,Liu, Caixing,Xu, Xueli,et al. Antiferromagnetism in two-dimensional polyradical nanosheets[J]. POLYMER CHEMISTRY,2018,9(46):6.
APA	Yang, Yang.,Liu, Caixing.,Xu, Xueli.,Meng, Zhi.,Tong, Wei.,...&Sheng, Zhigao.(2018).Antiferromagnetism in two-dimensional polyradical nanosheets.POLYMER CHEMISTRY,9(46),6.
MLA	Yang, Yang,et al."Antiferromagnetism in two-dimensional polyradical nanosheets".POLYMER CHEMISTRY 9.46(2018):6.

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