Synthesis of copper hexacyanoferrate nanoflake as a cathode for sodium-ion batteries

doi:10.1016/j.ceramint.2018.09.238

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Synthesis of copper hexacyanoferrate nanoflake as a cathode for sodium-ion batteries
	Ma, Xiao-Hang 1; Jia, Wei 1; Wang, Jiao 1; Zhou, Jia-Hao 1; Wu, Yao-Dong 1; Wei, Yi-Yong 1; Zi, Zhen-Fa 1; Da, Jian-Ming 2
刊名	CERAMICS INTERNATIONAL
	2019
卷号	45 期号:1 页码:740-746
关键词	Glycol-assisted coprecipitation method Copper hexacyanoferrate Nanoflake Cathode Sodium-ion batteries
ISSN号	0272-8842
DOI	10.1016/j.ceramint.2018.09.238
通讯作者	Zi, Zhen-Fa(zfzi@issp.ac.cn) ; Da, Jian-Ming(jmdai@issp.ac.cn)
英文摘要	Prussian blue analogues are considered as the promising cathodes for sodium-ion batteries. Since the electro-chemical properties are closely related to the morphology, the monodisperse copper hexacyanoferrate nano flakes with highly crystalline are synthesized by a glycol-assisted coprecipitation method and a tentative synthetic mechanism is proposed to explain the formation of nanostructures. The structure and electrochemical properties are characterized by X-ray photoelectron spectroscopy, FTIR spectra and galvanostatic cycle tests, respectively. Due to the novel architecture of copper hexacyanoferrate, a high electrochemical activity is obtained, resulting a high initial coulombic efficiency of 93%, a capacity retention of 73% at 1 degrees C after 300 cycles and 51 mAh g(-1) is maintained at high rate of 15 degrees C at 25 degrees C.
资助项目	NSFC[U16321611] ; NSFC[1274314] ; Postdoctoral Science Foundation of China[2016M590585] ; Education Department of Anhui Province[KJ2016A578] ; Nature Science Research Project of Anhui province[1808085QE154] ; Nature Science Research Project of Anhui province[1808085JQ13] ; Fund of Hefei Normal University[2016rcjj06] ; Fund of Hefei Normal University[2017QN06] ; Fund of Hefei Normal University[201714098080] ; Fund of Hefei Normal University[201714098076]
WOS关键词	PRUSSIAN BLUE ANALOGS ; SUPERIOR CATHODE ; ANODE MATERIALS ; RADIOACTIVE CESIUM ; CARBON NANOTUBES ; HIGH-CAPACITY ; LITHIUM ; REMOVAL ; NANOCUBES
WOS研究方向	Materials Science
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000452570300094
资助机构	NSFC ; NSFC ; NSFC ; NSFC ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; NSFC ; NSFC ; NSFC ; NSFC ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; NSFC ; NSFC ; NSFC ; NSFC ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; NSFC ; NSFC ; NSFC ; NSFC ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Postdoctoral Science Foundation of China ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Education Department of Anhui Province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Nature Science Research Project of Anhui province ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University ; Fund of Hefei Normal University
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/41005]
专题	合肥物质科学研究院_中科院固体物理研究所
通讯作者	Zi, Zhen-Fa; Da, Jian-Ming
作者单位	1.Hefei Normal Univ, Sch Phys & Mat Engn, Hefei 230601, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Ma, Xiao-Hang,Jia, Wei,Wang, Jiao,et al. Synthesis of copper hexacyanoferrate nanoflake as a cathode for sodium-ion batteries[J]. CERAMICS INTERNATIONAL,2019,45(1):740-746.
APA	Ma, Xiao-Hang.,Jia, Wei.,Wang, Jiao.,Zhou, Jia-Hao.,Wu, Yao-Dong.,...&Da, Jian-Ming.(2019).Synthesis of copper hexacyanoferrate nanoflake as a cathode for sodium-ion batteries.CERAMICS INTERNATIONAL,45(1),740-746.
MLA	Ma, Xiao-Hang,et al."Synthesis of copper hexacyanoferrate nanoflake as a cathode for sodium-ion batteries".CERAMICS INTERNATIONAL 45.1(2019):740-746.