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	Kernel Homology in Gold Nanoclusters
	Zhuang, Shengli1,2; Liao, Lingwen1,2; Yuan, Jinyun5; Wang, Chengming5; Zhao, Yan1,2; Xia, Nan1,2; Gan, Zibao1,2; Gu, Wanmiao1,2; Li, Jin4; Deng, Haiteng3
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2018-11-19
卷号	57期号:47页码:15450-15454
关键词	electrochemical properties functional group homology metal nanoclusters structural elucidation
ISSN号	1433-7851
DOI	10.1002/anie.201808997
通讯作者	Yang, Jinlong(jlyang@ustc.edu.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要	Homology is well known in organic chemistry; however, it has not yet been reported in nanochemistry. Herein, we introduce the concept of kernel homology to describe the phenomenon of metal nanoclusters sharing the same "functional group" in kernels with some similar properties. To illustrate this point, we synthesized two novel gold nanoclusters, Au-44(TBBT)(26) and Au-48(TBBT)(28) (TBBTH = 4-tert-butylbenzenethiol), and solved their total structures by X-ray crystallography, which reveals that they have the same Au-23 bi-icosahedron capped with a similar bottom cap (Au-6 and Au-8, respectively) in the kernels. The two novel gold nanoclusters, together with the existing Au-38(PET)(24) nanocluster (PETH= phenylethanethiol), have the same "functional group"-Au-23-in their kernels and have some similar properties (e.g., electrochemical properties); therefore, they are comparable to the homologues in organic chemistry.
资助项目	National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21573212] ; National Natural Science Foundation of China[21701179] ; National Natural Science Foundation of China[51502299] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21401064] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; Key Program of 13th five-year plan, CASHIPS[KP-2017-16] ; National Key R&D Program of China[2017YFA0207302] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002]
WOS关键词	CRYSTAL-STRUCTURE ; MONOLAYER ; CLUSTERS ; SILVER ; SIZE ; NANOPARTICLES ; AU-25 ; ELECTROCHEMISTRY ; TRANSITION ; EMERGENCE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000453344500025
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; National Key R&D Program of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/40930]
专题	合肥物质科学研究院_中科院固体物理研究所
通讯作者	Yang, Jinlong; Wu, Zhikun
作者单位	1.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Anhui, Peoples R China 3.Tsinghua Univ, Sch Life Sci, MOE Key Lab Bioinformat, Beijing 100084, Peoples R China 4.Tsinghua Univ, Sch Life Sci, Tsinghua Univ Peking Univ Joint Ctr Life Sci, Beijing 100084, Peoples R China 5.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhuang, Shengli,Liao, Lingwen,Yuan, Jinyun,et al. Kernel Homology in Gold Nanoclusters[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(47):15450-15454.
APA	Zhuang, Shengli.,Liao, Lingwen.,Yuan, Jinyun.,Wang, Chengming.,Zhao, Yan.,...&Wu, Zhikun.(2018).Kernel Homology in Gold Nanoclusters.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(47),15450-15454.
MLA	Zhuang, Shengli,et al."Kernel Homology in Gold Nanoclusters".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.47(2018):15450-15454.

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