Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice

doi:10.1002/cplu.201900017

	Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice
	Xu, Dan 1; Yang, Dazhi 1; Su, Jie 1; Gan, Liangbing 1,2
刊名	CHEMPLUSCHEM
	2019-06-01
卷号	84 期号:6 页码:608-612
关键词	alcoholysis aromatization fullerenes iminofuranones open-cage compounds
ISSN号	2192-6506
DOI	10.1002/cplu.201900017
通讯作者	Su, Jie(jie.su@pku.edu.cn) ; Gan, Liangbing(gan@pku.edu.cn)
英文摘要	A new type of open-cage [60]fullerene was prepared starting from our previously reported open-cage [60]fullerenes containing hydroxy and tert-butylperoxo groups, and an iminofuranone moiety on the rim of the orifice. The key reactions are alcoholysis with MeOH/PCl5 and reductive aromatization with SnCl2 or HI (aq). The resulting open-cage compound contains two ketone carbonyls, two amide carbonyls, and one ester carbonyl group. The X-ray crystal structure of the precursor compound shows that the 18-membered orifice is almost completely blocked because of the presence of the amide group directly above the orifice.
资助项目	NNSFC[21672009] ; NNSFC[21871015] ; MOST[2015CB856600]
WOS关键词	SKELETON BONDS ; FULLERENE ; C-60 ; DERIVATIVES ; CLEAVAGE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000470922000007
资助机构	NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/176051]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Su, Jie; Gan, Liangbing
作者单位	1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Xu, Dan,Yang, Dazhi,Su, Jie,et al. Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice[J]. CHEMPLUSCHEM,2019,84(6):608-612.
APA	Xu, Dan,Yang, Dazhi,Su, Jie,&Gan, Liangbing.(2019).Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice.CHEMPLUSCHEM,84(6),608-612.
MLA	Xu, Dan,et al."Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice".CHEMPLUSCHEM 84.6(2019):608-612.