hydridesamidesandimidesmediatedammoniasynthesisanddecomposition

	hydridesamidesandimidesmediatedammoniasynthesisanddecomposition
	Gao Wenbo; Guo Jianping; Chen Ping
刊名	chinesejournalofchemistry
	2019-01-01
卷号	37 期号:5 页码:442
ISSN号	1001-604X
英文摘要	Ammonia is feeding nearly half the world population and also holds the promise as a carbon-free energy carrier. The development of ammonia synthesis and decomposition processes under milder conditions is a grand challenge for more than a century. Increasing effort is devoted to this area in recent years and encouraging progress has been achieved. In this paper, we summarize our recent research using alkali or alkaline earth metal amides, imides and hydrides for ammonia synthesis and decomposition. These materials could serve as either indispensible component of active center in thermal catalytic process or nitrogen carrier for chemical looping ammonia synthesis. The synergy of amide, imide, or hydride with transition metals enables ammonia synthesis or decomposition with unprecedented high efficiency under milder reaction conditions, and thus opens an avenue to advance the chemistry or catalysis of N-2 fixation reaction. The compositional and structural diversity of the amide, imide and hydride materials provides plenty of opportunity and potential for further exploration and optimization.
资助项目	[National Natural Science Foundation of China] ; [Sino-Japanese Research Cooperative Program of Ministry of Science and Technology] ; [DICP] ; [Youth Innovation Promotion Association CAS] ; [Collaborative Innovation Center of Chemistry for Energy Materials (2011-iChEM)]
语种	英语
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/175678]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	中国科学院大连化学物理研究所
推荐引用方式 GB/T 7714	Gao Wenbo,Guo Jianping,Chen Ping. hydridesamidesandimidesmediatedammoniasynthesisanddecomposition[J]. chinesejournalofchemistry,2019,37(5):442.
APA	Gao Wenbo,Guo Jianping,&Chen Ping.(2019).hydridesamidesandimidesmediatedammoniasynthesisanddecomposition.chinesejournalofchemistry,37(5),442.
MLA	Gao Wenbo,et al."hydridesamidesandimidesmediatedammoniasynthesisanddecomposition".chinesejournalofchemistry 37.5(2019):442.