synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline

	synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline
	Lu YanLei 4; Zhu Ning 4; Zhao YuMeng 4; Lin Sen 4; Kuang XiaoNan 4; Li ZhongFeng 4; Xin XiuLan 2; Yang YuPing 3; Jin QiongHua 4; Zhang JiangWei 1
刊名	chinesejournalofinorganicchemistry
	2019-01-01
卷号	35 期号:4 页码:720
ISSN号	1001-4861
英文摘要	Two novel copper(I) complexes Cu(dppBz)(dpq)ClO4 (1) and Cu(dppe)(dpq)ClO4 (2) (dppBz=1,2-bis (diphenylphosphino)benzene, dppe=1,2-bis(diphenylphosphino)ethene, dpq=2,3-fpyrazino1,10phenanthroline) have been synthesized and characterized by X-ray diffraction, elemental analysis, infrared spectroscopy, absorption spectra, luminescent spectra, 11-1 NMR, 31P NMR spectroscopy and terahertz (THz) time-domain absorption spectroscopy. The central Cu(I) ion is chelated by a diimine ligand and a diphosphine ligand forming a distorted tetrahedron configuration for 1, and the configuration of 2 is similar to 1. The luminescent spectra of 2 indicated that the emission has metal-to-ligand charge transfer (MLCT) characteristics. The terahertz time-domain absorption spectroscopy analysis in a range of 0.2-2.8 THz showed that the absorption peaks at 0.40-0.90 THz are related to the coordination of the central Cu(I). CCDC: 1874580, 1; 1874581, 2.
语种	英语
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/174885]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.中国科学院大连化学物理研究所 2.陕西省地震局 3.中国科学院 4.中国科学院福建物质结构研究所
推荐引用方式 GB/T 7714	Lu YanLei,Zhu Ning,Zhao YuMeng,et al. synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline[J]. chinesejournalofinorganicchemistry,2019,35(4):720.
APA	Lu YanLei.,Zhu Ning.,Zhao YuMeng.,Lin Sen.,Kuang XiaoNan.,...&Zhang JiangWei.(2019).synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline.chinesejournalofinorganicchemistry,35(4),720.
MLA	Lu YanLei,et al."synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline".chinesejournalofinorganicchemistry 35.4(2019):720.