General Interfacial Self-Assembly Engineering for Patterning Two-Dimensional Polymers with Cylindrical Mesopores on Graphene

doi:10.1002/anie.201903684

	General Interfacial Self-Assembly Engineering for Patterning Two-Dimensional Polymers with Cylindrical Mesopores on Graphene
	Tian, Hao 2; Qin, Jieqiong 1,3; Hou, Dan 2; Li, Qian 2; Li, Chen 2; Wu, Zhong-Shuai 3; Mai, Yiyong 2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2019-07-22
卷号	58 期号:30 页码:10173-10178
关键词	2D nanomaterials block copolymers interface self-assembly mesoporous structures micro-supercapacitors
ISSN号	1433-7851
DOI	10.1002/anie.201903684
通讯作者	Wu, Zhong-Shuai(wuzs@dicp.ac.cn) ; Mai, Yiyong(mai@sjtu.edu.cn)
英文摘要	Free-standing 2D porous nanomaterials have attracted considerable interest as ideal candidates of 2D film electrodes for planar energy storage devices. Nevertheless, the construction of well-defined mesopore arrays parallel to the lateral surface, which facilitate fast in-plane ionic diffusion, is a challenge. Now, a universal interface self-assembly strategy is used for patterning 2D porous polymers, for example, polypyrrole, polyaniline, and polydopamine, with cylindrical mesopores on graphene nanosheets. The resultant 2D sandwich-structured nanohybrids are employed as the interdigital microelectrodes for the assembly of planar micro-supercapacitors (MSCs), which deliver outstanding volumetric capacitance of 102 F cm(-3) and energy density of 2.3 mWh cm(-3), outperforming most reported MSCs. The MSCs display remarkable flexibility and superior integration for boosting output voltage and capacitance.
资助项目	National Natural Science Foundation of China[51573091] ; National Natural Science Foundation of China[21774076] ; National Natural Science Foundation of China[51572259] ; National Natural Science Foundation of China[51872283] ; Program of the Shanghai Committee of Science and Technology[17JC1403200] ; Program of the Shanghai Committee of Science and Technology[19XD1421700] ; National Key R@D Program of China[2016YFB0100100] ; National Key R@D Program of China[2016YFA0200200] ; Natural Science Foundation of Liaoning Province[20180510038] ; DICP[ZZBS201708] ; DICP[ZZBS201802] ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS[DNL180310] ; DNL Cooperation Fund, CAS[DNL180308] ; DICPQIBEBT[UN201702] ; Program of Shanghai Eastern Scholar
WOS关键词	MICRO-SUPERCAPACITORS ; CARBON NANOSHEETS ; AQUEOUS-SOLUTIONS ; MOS2 NANOSHEETS ; RATE CAPABILITY ; ELECTRODE ; DESIGN ; FILMS ; OXIDE ; STATE
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000476452700019
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of the Shanghai Committee of Science and Technology ; Program of the Shanghai Committee of Science and Technology ; National Key R@D Program of China ; National Key R@D Program of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; DICP ; DICP ; Dalian National Laboratory For Clean Energy (DNL), CAS ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; DICPQIBEBT ; DICPQIBEBT ; Program of Shanghai Eastern Scholar ; Program of Shanghai Eastern Scholar ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of the Shanghai Committee of Science and Technology ; Program of the Shanghai Committee of Science and Technology ; National Key R@D Program of China ; National Key R@D Program of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; DICP ; DICP ; Dalian National Laboratory For Clean Energy (DNL), CAS ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; DICPQIBEBT ; DICPQIBEBT ; Program of Shanghai Eastern Scholar ; Program of Shanghai Eastern Scholar ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of the Shanghai Committee of Science and Technology ; Program of the Shanghai Committee of Science and Technology ; National Key R@D Program of China ; National Key R@D Program of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; DICP ; DICP ; Dalian National Laboratory For Clean Energy (DNL), CAS ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; DICPQIBEBT ; DICPQIBEBT ; Program of Shanghai Eastern Scholar ; Program of Shanghai Eastern Scholar ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of the Shanghai Committee of Science and Technology ; Program of the Shanghai Committee of Science and Technology ; National Key R@D Program of China ; National Key R@D Program of China ; Natural Science Foundation of Liaoning Province ; Natural Science Foundation of Liaoning Province ; DICP ; DICP ; Dalian National Laboratory For Clean Energy (DNL), CAS ; Dalian National Laboratory For Clean Energy (DNL), CAS ; DNL Cooperation Fund, CAS ; DNL Cooperation Fund, CAS ; DICPQIBEBT ; DICPQIBEBT ; Program of Shanghai Eastern Scholar ; Program of Shanghai Eastern Scholar
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/173809]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wu, Zhong-Shuai; Mai, Yiyong
作者单位	1.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China 2.Shanghai Jiao Tong Univ, Shanghai Key Lab Elect Insulat & Thermal Ageing, Sch Chem & Chem Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Tian, Hao,Qin, Jieqiong,Hou, Dan,et al. General Interfacial Self-Assembly Engineering for Patterning Two-Dimensional Polymers with Cylindrical Mesopores on Graphene[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(30):10173-10178.
APA	Tian, Hao.,Qin, Jieqiong.,Hou, Dan.,Li, Qian.,Li, Chen.,...&Mai, Yiyong.(2019).General Interfacial Self-Assembly Engineering for Patterning Two-Dimensional Polymers with Cylindrical Mesopores on Graphene.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(30),10173-10178.
MLA	Tian, Hao,et al."General Interfacial Self-Assembly Engineering for Patterning Two-Dimensional Polymers with Cylindrical Mesopores on Graphene".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.30(2019):10173-10178.